Mn(III)-Based Synthesis of 1,2-Dioxolanes, Reaction Mechanism, and Related Reaction
スポンサーリンク
概要
- 論文の詳細を見る
The manganese(III)-based aerobic oxidation of arylacetylenes with 2,4-pentanedione at ambient temperature unexpectedly gave the 1,2-dioxolane derivatives in moderate yields together with a small amount of the oxiranes. The 1,2-dioxolanes underwent silica gel-assisted contraction to quantitatively give the oxiranes. The reaction pathway for the formation of the 1,2-dioxolanes and the by-product was discussed.
著者
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Kurosawa Kazu
Department Of Chemistry Kumamoto University
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Kurosawa Kazu
Department Of Chemistry Faculty Of Science Kumamoto University
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Nishino Hiroshi
Department Of Chemistry Kumamoto University
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Tsubusaki Takuma
Department of chemistry, Kumamoto University
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Tsubusaki Takuma
Department Of Chemistry Kumamoto University
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Nishino Hiroshi
Department Of Chemistry Faculty Of Science
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Nishino Hiroshi
Department Of Applied Chemistry The National Defense Academy
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Nishino Hiroshi
Department Of Applied Chemistry National Defense Academy
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