Mn(III)-Based One-Pot Synthesis of Spiro- and Benzocycloalka[1,2-b]furans and Their Acid-Catalyzed Trasformation
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概要
- 論文の詳細を見る
Spiro[furan-2(3H),1'-(benzocycloalkane)]derivatives were obtained by the oxidation of methylenebenzocycloalkaneswith manganese(III) acetate in the presence of 1,3-dicarbonyl compounds. A similar oxidation of the benzocycloalkene derivatives produced the benzocycloalka[1,2-b]furans in good yields. However, 1-benzyl-3,4-dihydronaphthalene gave both the corresponding spirofuran and benzocyclohexa[1,2-b]furan under the same oxidation conditions. The acid-catalyzed ring-opening reaction of the spirofurans and benzocycloalka[1,2-b]furans was also investigated.
- 熊本大学の論文
著者
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Nishino Hiroshi
Department Of Applied Chemistry The National Defense Academy
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Fujino Reika
Department Of Materials And Life Science Graduate School Of Science And Technology Kumamoto Universi
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Nishino Hiroshi
Department Of Applied Chemistry National Defense Academy
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Nishino Hiroshi
Department of Chemistry, Faculty of Science,Kumamoto University
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