Abstraction of Methyl Hydrogen of Organosilicon Compounds by <I>t</I>-Butoxy Radicals

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概要

• 論文の詳細を見る
• 公益社団法人 日本化学会の論文

著者

• Hosomi Akira

  Department Of Chemistry And Graduate School Of Chemistry University Of Tsukuba

• Kumada Makoto

  Department Of Applied Chemistry And Chemical Engineering Yamaguchi University

• Sakurai Hideki

  Department Of Chemistiy Faculty Of Science Tohoku University

• Sakurai Hideki

  Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University

関連論文

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• Vesicle-mediated Protein Transport Pathways to the Vacuole in Schizosaccharomyces pombe
• Photoreaction via Non-Resonant Two-Photon Excitation. Selective Silylene Extrusion from 2,2-Diphenyltrisilane
• EVALUATION OF ENDOSCOPIC HEMORRHOIDAL LIGATION IN 119 PATIENTS
• Intramolecular Oligomerization of Disilalkylene{-Me_2Si(CH_2)_nSiMe_2-}Bridged Cyclic Triacetylenes^1
• Novel 1,2-Dilithiodisilanes Derived from Reduction of Stable Tetrakis(trialkylsilyl)disilenes with Lithium Metal
• Synthesis and Structure of a Stable Cyclic Dialkylgermylene
• Bimolecular Reactions of Tetrakis(trialkylsilyl)disilenes with Various Reagents
• Stereoselective Allylation of β-Hydroxy-and β-Amino-α,β-enones with Allyltrifluorosilane/Triethylamine Systems^1
• Preparation, Structure, and Photochemistry of 2-Disilanyl-1,4-benzoquinones
• Synthesis, Structure, and Photochemistry of 2,3,5,6-Tetrasilyl-1,4-benzoquinones and Related Compounds
• Synthesis, Structure, and Photochemistry of Tetrakis(trimethylsilyl)-p-benzoquinone
• Synthesis and Reduction of Octasilyl[4]radialene. Structure and Dynamic Study of [4]Radialene Dianion with Eight-Center Ten-Electron π-System
• Persilylated Dimethylenecyclobutene Dianion Dilithium as the First 6C-8π Allyl Anion System
• The Reaction of Disilylacetylenes with Cyclopentadienyl Manganese. Formation of Vinylidene Complexes by 1, 2-Silyl Shift
• Syntheses of Dialkali Metal Complexes of Tetrakis(dimethylsilyl)ethylene : [(HMe_2Si)_2C=C(SiMe_2H)_2]^[M^+(ligande)_n]_ Evidence for siH-Alkali Metal Agostic Interactions
• Highly Twisted Ethylene Dianion Dilithium Stabilized by Phenyl and Silyl Groups
• Dianion Dialkali Metals of 2,2',5,5'-Tetrasilabicyclopentylidene. Synthesis and Crystal Structures
• Structure of 1,2-Dilithio[tetrakis(trimethylsilyl)]ethane in Solution. Observation of Lithium-Bridged Structures and Unexpected Anionic Rearrangement
• Enantioselective Allylation of Aldehydes Using Tartrate Eastr Modified Allylsilanes
• A New Mode of Fluoride-Ion Exchange Reactions between Tetracoordinate Silane and Pentacoordinate Fluorosilicate
• Synthesis and Structure of Hexacoordinate Organosilicon Compounds Having Tropolonato Ligands^1
• p-and m-Phenylenebis[trifluoro(phenyl)silicates] and Related Monosilicates
• Silyl-Substituted Dilithium Salt of Fulvene Dianion with 6 Center/8 Electron π-System : Synthesis and Characterization
• Intramolecular Carbostannylation of Allyl- and Vinylstannanes via a Radical Chain Process
• Hydroxy Group-Directed Homolytic Hydrostannylation of Alkenols with Dibutylchlorostannane
• A Novel and Efficient Generation of Functionalized Vinylcopper Reagents and their Reactions with Electrophiles. Synthesis of β-Methylthiobutenolides
• Crystal Structures of Unsolvated Lithiosilanes with Si-Si Bonds
• Lithiosilanes with Si-Si Bonds : Synthesis and ^6Li, ^7Li, and ^Si NMR Studies
• Indium(III)-catalyzed Coupling between Alkynes and Aldehydes to α,β-Unsaturated Ketones
• Synthesis of Disilacycloalkenes by Ruthenium Alkylidene Catalyzed Ring-Closing Metathesis (RCM) Reaction of α,ω-Bis(allyldimethylsilyl)-Substituted Compounds
• Molecular Structure and Photochemical Reactions of Trimethylsilylmethyl-Substituted Masked Disilene^1
• Kinetics of Chain Organization at the Thermochromic Transition of Polysilanes^1
• Generation and Trapping of Bis(dialkylamino)silylenes : Experimental Evidence for Bridged Structure of Diaminosilylene Dimers
• Platinum(II)-catalyzed Annulation of 5-Methyl-5-hexen-1-ols with Aldehydes
• Synthesis and Mesomorphic Properties of 1, 10-Dialkylpermethyldecasilanes
• Synthesis of Cyclotetragermanes of the Type of [R(Ph)Ge]_4 and Conversion to [R(Cl)Ge]_4. The First Functionalized Cyclotetragemanes
• Platinum(II)-catalyzed Acetal-Ene Reaction : Easy Access to Homoallylic Ethers
• Efficient Alkenation of Aldehydes and Ketones to α,β-Unsaturated Esters Using α,α-Bis(dimethylsilyl)-substituted Esters
• Silole-core Dendrimers : A Facile Synthesis and Photophysical Properties
• Polysilane-Silica Hybrid Nanoparticles
• Metal Nanoparticles Derived from Polysilane Shell Cross-linked Micelle Templates
• PXA Domain-Containing Protein Pxa1 Is Required for Normal Vacuole Function and Morphology in Schizosaccharomyces pombe
• Acid-Catalyzed Cyclization of Vinylsilanes Bearing a Hemiacetal Group^1
• New Access to Cross-Coupling Reaction between Arylsilanes or Heteroarylsilanes and Aryl Halides Mediated by a Copper(I)Salt^1
• Introduction of Electrophiles to the α-Position of α,β-Unsaturated Aldehydes and Ketones by Sequential Conjugate Aminosilylation-Alkylation-Deamination
• Development of New Reagents Containing Silicon and Related Metals and Application to Practical Organic Syntheses
• Allenymethylsilane Derivative as a Synthetic Equivalent of 1, 2, 3-Butatriene:Synthesis and Reactions of Di-exo-methylenecyclobutanes and-cyclobutenes
• Alkoxymethylthiomethylsilanes as a Synthetic Equivalent of Thiocarbonyl Ylides. Synthesis of 1,3-Oxathiolanes and Tetrahydrothiophenes
• Tandem Aldol-Reduction Reaction of Dimethylsilyl Enolates:A New Method for Stereoselective Preparation of 1, 3-Diols
• Anionic Polymerization of Tetraphenylgermole-spiro-cyclogermatetrasilane.A Striking Contrast in the Mechanism to the Corresponding Silole Case^1
• Intramolecular DImerization of Silylenes Leading to Novel Cyclic Disilenes^1
• The Induction of a Helical Conformation in Polysilanes with an Optically Active Terminal Group
• Anionic Ring Opening Polymerization of Octamethyltetrasilacyclopentane^1
• Dynamics of Polysilane Chain in Dilute Solution as Studied by Spin Labeling^1
• Thermochromic Behavior of Polysilanes Concerning the Dependence on the Sequence Length
• Molecular Structure of Phenyl[tris(trimethylsilyl)]ethylene Dilithimu Complex. An Orthogonal Dianion
• Synthesis, Properties, and Reactions of Hexasilyl-3,3'-bicyclopropenyls and Related Compounds
• Photochemistry of Disilanylcyclohexenones. ESR Detection of a Novel Silatrimethylenemethane Intermediate
• Extraordinary Large Red Shift of the n(Si)→3p(Si) Transition of Silylenes Caused by Trimethylsilyl and Trimethylgermyl Substituents
• Measurement and Prediction of Mutual Diffusion Coefficients for Acrylic Adhesive-Methyl Propyl Ketone System
• An NMR Study of the Formation of N-Silylacetonitrilium Ions by Using Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as Counteranion1
• Siloxycarbenium Tetrakis[3,5-bis(trifluoromethyl)phenyl]borates and Their Role in Reactions of Ketones with Nucleophiles^
• Schizosaccharomyces pombe Pep12p is required for vacuolar protein transport and vacuolar homotypic fusion(GENETICS, MOLECULAR BIOLOGY, AND GENE ENGINEERING)
• CUE Domain-Containing Protein Vps901 Is Required for Vacuolar Protein Transport in Schizosaccharomyces pombe
• CUE Domain-Containing Protein Vps901 Is Required for Vacuolar Protein Transport in Schizosaccharomyces pombe
• Organofluorosilicates in organic synthesis. XVI. Synthesis of organo-pentafluorosilicates via the Diels-Alder, ene, and Friedel-Crafts reaction. Their transformations to organic halides and alcohols.
• New synthesis and Diels-Alder reactions of 2-aminomethyl-1,3-butadienes and related 1,3-dienes.
• On the mechanism of uncatalyzed reduction of triphenylmethyl chloride with triethylgermane.
• Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. I. Preparation of chiral ferrocenylphosphines.
• Preparation, characterization and stereochemistry of 2-methyl-2-silabicyclo(2.2.1)heptane derivatives.
• Stereochemistry of a chiral germyl radical in the reaction of carbon tetrachloride.
• Stereoselective cross-aldol reactions of silyl enol ethers with acetals catalyzed by iodotrimethylsilane.
• Determination of Enantiomeric Purity of 1-Phenylalkanols Using a Chiral NMR Shift Reagent
• Preparation of (R)-N,N-dimethyl-1-(2-(diphenylphosphino)ferrocenyl)-2-propanamines and asymmetric Grignard cross-coupling catalyzed by nickel complexes with the phosphine ligands.
• Silicon–Carbon Unsaturated Compounds. XVI. Photorearrangement of an Adduct Derived from Reaction of a Silicon–Carbon Unsaturated Compound with t-Butyl Alcohol
• Nickel-phosphine complex-catalyzed Grignard coupling. I. Cross-coupling of alkyl, aryl, and alkenyl Grignard reagents with aryl and alkenyl halides: General scope and limitations.
• The Reaction of Hydrosilanes with Chlorosilanes in the Presence of Grignard Reagents. A New Method of Silicon-Silicon Bond Formation
• Relative Reactivities in the Addition of Free Trichloromethyl Radicals to Substituted Styrenes. An Attempt to Separate Polar and Resonance Effects
• Conformationally stable 1-substituted 1-methyl-4-t-butyl-1-silacyclohexanes, a new organosilicon system suitable for stereochemical studies.
• Silyl Radicals. X. On the Mechanism of Uncatalyzed Reduction of Carbon Tetrachloride with Polysilicon Hydride
• A New Oxygen-Insertion Reaction into Silicon-Silicon Bonds with Tertiary Amine Oxides
• The reaction of the butenyl Grignard reagent with trimethylchlorosilane.
• Abstraction of Methyl Hydrogen of Organosilicon Compounds by t-Butoxy Radicals
• Silyl radicals. XV. Stereochemical course of chlorine abstraction by 1-methyl-4-t-butyl-1-silacyclohexyl radicals from polychloroalkane.

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