The reaction of the butenyl Grignard reagent with trimethylchlorosilane.
スポンサーリンク
概要
- 論文の詳細を見る
The reaction of trimethylchlorosilane with the butenyl Grignard reagent prepared from either 3-chloro-1-butene or 1-chloro-2-butene yielded <I>trans</I>-2-butenyltrimethylsilane, <I>cis</I>-2-butenyltrimethylsilane and 1-methyl-2-propenyltrimethylsilane, approximately in the ratio of 30/20/50. Structures of these isomeric butenylsilanes were elucidated by NMR and IR spectra.
- 公益社団法人 日本化学会の論文
著者
-
Sakurai Hideki
Department Of Chemistiy Faculty Of Science Tohoku University
-
Kudo Yoshihiko
Department of Chemistry, Faculty of Science, Tohoku University
-
Miyoshi Heiichi
Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University
関連論文
- Photoreaction via Non-Resonant Two-Photon Excitation. Selective Silylene Extrusion from 2,2-Diphenyltrisilane
- EVALUATION OF ENDOSCOPIC HEMORRHOIDAL LIGATION IN 119 PATIENTS
- Intramolecular Oligomerization of Disilalkylene{-Me_2Si(CH_2)_nSiMe_2-}Bridged Cyclic Triacetylenes^1
- Novel 1,2-Dilithiodisilanes Derived from Reduction of Stable Tetrakis(trialkylsilyl)disilenes with Lithium Metal
- Synthesis and Structure of a Stable Cyclic Dialkylgermylene
- Bimolecular Reactions of Tetrakis(trialkylsilyl)disilenes with Various Reagents
- Stereoselective Allylation of β-Hydroxy-and β-Amino-α,β-enones with Allyltrifluorosilane/Triethylamine Systems^1
- Preparation, Structure, and Photochemistry of 2-Disilanyl-1,4-benzoquinones
- Synthesis, Structure, and Photochemistry of 2,3,5,6-Tetrasilyl-1,4-benzoquinones and Related Compounds
- Synthesis, Structure, and Photochemistry of Tetrakis(trimethylsilyl)-p-benzoquinone
- Synthesis and Reduction of Octasilyl[4]radialene. Structure and Dynamic Study of [4]Radialene Dianion with Eight-Center Ten-Electron π-System
- Persilylated Dimethylenecyclobutene Dianion Dilithium as the First 6C-8π Allyl Anion System
- The Reaction of Disilylacetylenes with Cyclopentadienyl Manganese. Formation of Vinylidene Complexes by 1, 2-Silyl Shift
- Syntheses of Dialkali Metal Complexes of Tetrakis(dimethylsilyl)ethylene : [(HMe_2Si)_2C=C(SiMe_2H)_2]^[M^+(ligande)_n]_ Evidence for siH-Alkali Metal Agostic Interactions
- Highly Twisted Ethylene Dianion Dilithium Stabilized by Phenyl and Silyl Groups
- Dianion Dialkali Metals of 2,2',5,5'-Tetrasilabicyclopentylidene. Synthesis and Crystal Structures
- Structure of 1,2-Dilithio[tetrakis(trimethylsilyl)]ethane in Solution. Observation of Lithium-Bridged Structures and Unexpected Anionic Rearrangement
- Enantioselective Allylation of Aldehydes Using Tartrate Eastr Modified Allylsilanes
- A New Mode of Fluoride-Ion Exchange Reactions between Tetracoordinate Silane and Pentacoordinate Fluorosilicate
- Synthesis and Structure of Hexacoordinate Organosilicon Compounds Having Tropolonato Ligands^1
- p-and m-Phenylenebis[trifluoro(phenyl)silicates] and Related Monosilicates
- Silyl-Substituted Dilithium Salt of Fulvene Dianion with 6 Center/8 Electron π-System : Synthesis and Characterization
- Crystal Structures of Unsolvated Lithiosilanes with Si-Si Bonds
- Lithiosilanes with Si-Si Bonds : Synthesis and ^6Li, ^7Li, and ^Si NMR Studies
- Synthesis of Disilacycloalkenes by Ruthenium Alkylidene Catalyzed Ring-Closing Metathesis (RCM) Reaction of α,ω-Bis(allyldimethylsilyl)-Substituted Compounds
- Molecular Structure and Photochemical Reactions of Trimethylsilylmethyl-Substituted Masked Disilene^1
- Kinetics of Chain Organization at the Thermochromic Transition of Polysilanes^1
- Generation and Trapping of Bis(dialkylamino)silylenes : Experimental Evidence for Bridged Structure of Diaminosilylene Dimers
- Synthesis and Mesomorphic Properties of 1, 10-Dialkylpermethyldecasilanes
- Synthesis of Cyclotetragermanes of the Type of [R(Ph)Ge]_4 and Conversion to [R(Cl)Ge]_4. The First Functionalized Cyclotetragemanes
- Silole-core Dendrimers : A Facile Synthesis and Photophysical Properties
- Polysilane-Silica Hybrid Nanoparticles
- Metal Nanoparticles Derived from Polysilane Shell Cross-linked Micelle Templates
- Anionic Polymerization of Tetraphenylgermole-spiro-cyclogermatetrasilane.A Striking Contrast in the Mechanism to the Corresponding Silole Case^1
- Intramolecular DImerization of Silylenes Leading to Novel Cyclic Disilenes^1
- The Induction of a Helical Conformation in Polysilanes with an Optically Active Terminal Group
- Anionic Ring Opening Polymerization of Octamethyltetrasilacyclopentane^1
- Dynamics of Polysilane Chain in Dilute Solution as Studied by Spin Labeling^1
- Thermochromic Behavior of Polysilanes Concerning the Dependence on the Sequence Length
- Molecular Structure of Phenyl[tris(trimethylsilyl)]ethylene Dilithimu Complex. An Orthogonal Dianion
- Synthesis, Properties, and Reactions of Hexasilyl-3,3'-bicyclopropenyls and Related Compounds
- Photochemistry of Disilanylcyclohexenones. ESR Detection of a Novel Silatrimethylenemethane Intermediate
- Extraordinary Large Red Shift of the n(Si)→3p(Si) Transition of Silylenes Caused by Trimethylsilyl and Trimethylgermyl Substituents
- An NMR Study of the Formation of N-Silylacetonitrilium Ions by Using Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as Counteranion1
- Siloxycarbenium Tetrakis[3,5-bis(trifluoromethyl)phenyl]borates and Their Role in Reactions of Ketones with Nucleophiles^
- On the mechanism of uncatalyzed reduction of triphenylmethyl chloride with triethylgermane.
- Preparation, characterization and stereochemistry of 2-methyl-2-silabicyclo(2.2.1)heptane derivatives.
- Stereochemistry of a chiral germyl radical in the reaction of carbon tetrachloride.
- Stereoselective cross-aldol reactions of silyl enol ethers with acetals catalyzed by iodotrimethylsilane.
- The Reaction of Hydrosilanes with Chlorosilanes in the Presence of Grignard Reagents. A New Method of Silicon-Silicon Bond Formation
- Relative Reactivities in the Addition of Free Trichloromethyl Radicals to Substituted Styrenes. An Attempt to Separate Polar and Resonance Effects
- Conformationally stable 1-substituted 1-methyl-4-t-butyl-1-silacyclohexanes, a new organosilicon system suitable for stereochemical studies.
- Silyl Radicals. X. On the Mechanism of Uncatalyzed Reduction of Carbon Tetrachloride with Polysilicon Hydride
- A New Oxygen-Insertion Reaction into Silicon-Silicon Bonds with Tertiary Amine Oxides
- The reaction of the butenyl Grignard reagent with trimethylchlorosilane.
- Abstraction of Methyl Hydrogen of Organosilicon Compounds by t-Butoxy Radicals
- Silyl radicals. XV. Stereochemical course of chlorine abstraction by 1-methyl-4-t-butyl-1-silacyclohexyl radicals from polychloroalkane.