Synthesis, Structure, and Photochemistry of 2,3,5,6-Tetrasilyl-1,4-benzoquinones and Related Compounds

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概要

• 論文の詳細を見る
• Chemical Society of Japanの論文
• 2002-12-15

著者

• Kabuto C

  Research And Analytical Center For Giant Molecules Graduate School Of Science Tohoku University

• KABUTO Chizuko

  Department of Chemistry, Faculty of Science, Tohoku University

• SAKURAI Hideki

  Department of Chemistry, Faculty of Science, Tohoku University

• Sakurai Hiroshi

  Department Of Material And Biological Chemistry Faculty Of Science Yamagata University

• Sakurai H

  Department Of Basic Science Graduate School Of Arts And Sciences The University Of Tokyo

• Ebata Keisuke

  Department Of Chemistry Graduate School Of Science Tohoku University

• Sakurai H

  Gakushuin Univ. Tokyo

• Kabuto Chizuko

  Department Of Chemistry Faculty Of Science Tohoku University

• TSUTSUI Shinobu

  Photodynamics Research Center, The Institute of Physical and Chemical Research (RIKEN)

• SAKAMOTO Kenkichi

  Department of Chemistry, Graduate School of Science, Tohoku University

• Tsutsui S

  Photodynamics Research Center The Institute Of Physical And Chemical Research(riken)

• Tsutsui Shinobu

  Photodynamics Research Center The Institute Of Physical And Chemical Research (riken)

• Sakamoto K

  Department Of Chemistry Graduate School Of Science Tohoku University

• Sakamoto Kenkichi

  Department Of Chemistry Faculty Of Science Tohoku University

• Sakurai H

  Department Of Chemistry Graduate School Of Science Tohoku University

• Sakurai Hideki

  Department Of Chemistiy Faculty Of Science Tohoku University

関連論文

• Synthesis of Isochalcogenazole Rings by Treating β-(N,N-Dimethylcarbamoylchalcogenenyl)alkenyl Ketones with Hydroxylamine-O-sulfonic Acid
• Synthesis and Oxidative Ring Contraction of 1,5,3,7-Dichalcogena-diazocanes. Novel Formation of 1,2,4-Diselenazolidines, 1,2,4-Ditellurazolidines, and 1,2,3,4,5,7-Pentathiazocanes
• Novel Synthesis and Thermal Ring Fission of 7-Aryl-1,2,3,4,5,7-pentathiazocanes
• Generation of 1,3-Chalcogenaza-1,3-butadienes by Thermal Cycloreversion of 2,4,6-Trisubstituted 6H-1,3,5-Oxachalcogenazines
• Synthesis of 1, 2, 4-Ditellurazolidines by Oxidative Ring Contraction of 2H, 6H-Tetrahydro-1, 5, 3, 7-ditelluradiazocines
• Formation of Kinetically Stabilized Dithiiranes by Treating Thione S-Oxides Bearing a Bulky Substituent with Lawesson's Reagent
• Synthesis of Dialkenyl Dichalcogenides via Alkenechalcogenolate Ions Generated by Treating Ketone p-Toluenesulfonylhydrazones with a Base and Elemental Chalcogen
• A Novel Conversion of 3,7-Disubstituted 2H,6H-Tetrahydro-1,5,3,7-diselenadiazocines to 4-Substituted 1,2,4-Diselenazolidines by Treating with Oxidizing Agents
• Novel Generation, Characterization, and Trapping of 2-Methylene-3-cyclobutene-1-selones
• Photoreaction via Non-Resonant Two-Photon Excitation. Selective Silylene Extrusion from 2,2-Diphenyltrisilane
• アセタール構造を有する不斉配位子の創製とそのパラジウム触媒不斉反応への応用
• LIPASE-CATALYZED RESOLUTION AND ABSOLUTE CONFIGURATION OF PHOTOPYRIDONES
• Coordination of Epithio Groups of p - tert - Butylthiacalix [4]arene in a Zn^ Complex Studied by X-Ray Crystallography
• A New Reaction of Adenine with a 1,4-Anhydroribitol Having a Vicinal cis-Oriented Azide and O-Tosylate: Formation of a Novel Aziridinoadenine Isonucleoside
• Selective Si-Si Bond Cleavage of Decaisopropylbicyclo[2.2.0]hexasilane with Hydrobromic Acid and Hydrochloric Acid
• Highly Planar Silane[(i-Pr)_3Si]_3SiH and Silyl Radical[(i-Pr)_3Si]_3Si・
• Structure and Unusual Electronic Spectra of Decaisopropyl-7-oxabicyclo[2.2.1]heptasilane
• EVALUATION OF ENDOSCOPIC HEMORRHOIDAL LIGATION IN 119 PATIENTS
• Intramolecular Oligomerization of Disilalkylene{-Me_2Si(CH_2)_nSiMe_2-}Bridged Cyclic Triacetylenes^1
• 1,3-Digermabicyclo[1.1.0]butane with an Inverted Bridge Ge-Ge σ Bond
• Synthesis of Tricyclo[3.1.0.0^]hexasilane and Its Photochemical Isomerization to Tricyclo[2.2.0.0^]hexasilane
• Dinuclear Palladium Complex with a Bridging Dialkylsilylene Ligand
• Unexpected Reactions of an Isolable Dialkylsilylene with Haloalkanes
• Novel 1,2-Dilithiodisilanes Derived from Reduction of Stable Tetrakis(trialkylsilyl)disilenes with Lithium Metal
• Synthesis and Structure of a Stable Cyclic Dialkylgermylene
• Bimolecular Reactions of Tetrakis(trialkylsilyl)disilenes with Various Reagents
• Stereoselective Allylation of β-Hydroxy-and β-Amino-α,β-enones with Allyltrifluorosilane/Triethylamine Systems^1
• Preparation, Structure, and Photochemistry of 2-Disilanyl-1,4-benzoquinones
• Synthesis, Structure, and Photochemistry of 2,3,5,6-Tetrasilyl-1,4-benzoquinones and Related Compounds
• Synthesis, Structure, and Photochemistry of Tetrakis(trimethylsilyl)-p-benzoquinone
• Synthesis and Reduction of Octasilyl[4]radialene. Structure and Dynamic Study of [4]Radialene Dianion with Eight-Center Ten-Electron π-System
• Persilylated Dimethylenecyclobutene Dianion Dilithium as the First 6C-8π Allyl Anion System
• Ring-Opening Reactions of anti-Dodecaisopropyltricyclo [4. 2. 0. 0^] octasilane. Formation of Novel Bicyclo [3. 3. 0] octasilane and Bicyclo [4. 2. 0] octasilane Systems
• Regulation of Main-Chain Conformation of Permethyldecasilane by Complexation with γ-Cyclodextrin
• Preparation of Hyperbranched Polymethacrylates by Self-Condensing Group Transfer Polymerization
• The Reaction of Disilylacetylenes with Cyclopentadienyl Manganese. Formation of Vinylidene Complexes by 1, 2-Silyl Shift
• Synthesis, Structure, and Photochemistry of 2-Silyl-and 2-Disilanyl-2-aryl-1, 3-dithiane Derivatives
• Syntheses of Dialkali Metal Complexes of Tetrakis(dimethylsilyl)ethylene : [(HMe_2Si)_2C=C(SiMe_2H)_2]^[M^+(ligande)_n]_ Evidence for siH-Alkali Metal Agostic Interactions
• Synthesis and Structure of a Series of Oligo[1, 1-(2, 3, 4, 5-tetramethylsilole)]s
• Highly Twisted Ethylene Dianion Dilithium Stabilized by Phenyl and Silyl Groups
• Dianion Dialkali Metals of 2,2',5,5'-Tetrasilabicyclopentylidene. Synthesis and Crystal Structures
• Structure of 1,2-Dilithio[tetrakis(trimethylsilyl)]ethane in Solution. Observation of Lithium-Bridged Structures and Unexpected Anionic Rearrangement
• A Molecular Gyroscope Having Phenylene Rotator Encased in Three-spoke Silicon-based Stator
• Trimethylsilyl-substituted Dibenzodehydro[12]annulene Having High Thermal and Chemical Stability
• Phenylene-bridged Polysilaalkane Macrocycles as Framed Molecular Rotor
• Hydrogenation of Silyl-Substituted Alkynes Using Diimide: Application to the Synthesis of Saturated Sila-Macrocycles
• X-Ray Crystal Structure and Dynamic Behavior of Pentafluoro-9,10-disila-9,10-dihydroanthracene anion Salts Having Transannular 1.4-Fluorine Bridge
• An ESR Study of a Tetrasilaspirobiindane Anion Radical. Stereoelectronic Electron - Accepting Effects of Trialkylsilyl Groups
• Enantioselective Allylation of Aldehydes Using Tartrate Eastr Modified Allylsilanes
• A New Mode of Fluoride-Ion Exchange Reactions between Tetracoordinate Silane and Pentacoordinate Fluorosilicate
• Synthesis and Structure of Hexacoordinate Organosilicon Compounds Having Tropolonato Ligands^1
• p-and m-Phenylenebis[trifluoro(phenyl)silicates] and Related Monosilicates
• Preparation and Properties of 2,2-Bissilyl-1,3-dithia-2-silacyclopent-4-enes and Related Compounds
• Silyl-Substituted Dilithium Salt of Fulvene Dianion with 6 Center/8 Electron π-System : Synthesis and Characterization
• Metal-Ion Induced Intramolecular Charge-Transfer Fluorescence of p-Pentamethyldisilanylacetophenone
• Crystal Structures of Unsolvated Lithiosilanes with Si-Si Bonds
• Role of the Heteroatoms in the Complex Metal Hydride Reduction of 2-t-Butyl-1, 3-dioxan-5-one and 3-Oxoquinolizidine : Comparison of Their Reactivity and Stereochemistry with Those of the Corresponding Carbocyclic Compounds
• Lithiosilanes with Si-Si Bonds : Synthesis and ^6Li, ^7Li, and ^Si NMR Studies
• The Roles of 2- and 3-Axial Methoxy Groups in Determining the Stereochemistry of the Complex Metal Hydride Reduction of Cyclohexanones : Examination of the Cieplak Model
• Generation of 1, 3-Selenaza-1, 3-butadienes by Thermal Cycloreversion of 2, 4, 6-Trisubstituted 6H-1, 3, 5-Oxaselenazines
• Palladium-Catalyzed Synthesis of α-Diketones from Acylchromates, Indoarenes, and Carbon Monoxide
• Synthesis of Disilacycloalkenes by Ruthenium Alkylidene Catalyzed Ring-Closing Metathesis (RCM) Reaction of α,ω-Bis(allyldimethylsilyl)-Substituted Compounds
• Palladium Catalyzed Coupling Reaction of Acylchromate Complexed and Allylic Bromides
• A Novel Rearrangement of Chromium Allyloxy(aryl) carbene Complexes Catalyzed by Pd(0)
• Molecular Structure and Photochemical Reactions of Trimethylsilylmethyl-Substituted Masked Disilene^1
• Kinetics of Chain Organization at the Thermochromic Transition of Polysilanes^1
• Generation and Trapping of Bis(dialkylamino)silylenes : Experimental Evidence for Bridged Structure of Diaminosilylene Dimers
• Synthesis and Mesomorphic Properties of 1, 10-Dialkylpermethyldecasilanes
• NO Decomposition in the Presence of Excess O_2 Using the Electrochemical Cells with Pd Electrodes Treated at High Temperature and Coated with La_Sr_xCoO_3
• Synthesis of Cyclotetragermanes of the Type of [R(Ph)Ge]_4 and Conversion to [R(Cl)Ge]_4. The First Functionalized Cyclotetragemanes
• Synthesis of New Vanadyl Complexes of Hydroxyazine-type Heterocycles and Their Insulin-Mimetic Activities
• Ground State Triplet Cation Diradicals Generated from N, N-Dimethylamino Nitronyl Nitroxide and Its Homologues through One-Electron Oxidation
• Protective Effects of Hydroxybenzoic Acids and Their Esters on Cell Damage Induced by Hydroxyl Radicals and Hydrogen Peroxides
• Bissilyl Ketone ; A Convenient Method for the Synthesis and Its Pd(0)Catalyzed Reaction with Alkenes and Alkynes
• Addition of HCl to a Base-Stabilized Hydrido (silylene) tungsten Complex and Reactivity of the Adduct toward LiAlH_4
• Silole-core Dendrimers : A Facile Synthesis and Photophysical Properties
• Polysilane-Silica Hybrid Nanoparticles
• Metal Nanoparticles Derived from Polysilane Shell Cross-linked Micelle Templates
• Anionic Polymerization of Tetraphenylgermole-spiro-cyclogermatetrasilane.A Striking Contrast in the Mechanism to the Corresponding Silole Case^1
• Intramolecular DImerization of Silylenes Leading to Novel Cyclic Disilenes^1
• The Induction of a Helical Conformation in Polysilanes with an Optically Active Terminal Group
• Anionic Ring Opening Polymerization of Octamethyltetrasilacyclopentane^1
• Dynamics of Polysilane Chain in Dilute Solution as Studied by Spin Labeling^1
• Thermochromic Behavior of Polysilanes Concerning the Dependence on the Sequence Length
• Preparation and Characterization of Gold Nano-Particles Chemisorbed by π-Radical Thiols
• Molecular Structure of Phenyl[tris(trimethylsilyl)]ethylene Dilithimu Complex. An Orthogonal Dianion
• Synthesis of Tungsten Thienyl Complexes via C-H Bond Activation of Thiophenes
• Synthesis, Properties, and Reactions of Hexasilyl-3,3'-bicyclopropenyls and Related Compounds
• Photochemistry of Disilanylcyclohexenones. ESR Detection of a Novel Silatrimethylenemethane Intermediate
• Extraordinary Large Red Shift of the n(Si)→3p(Si) Transition of Silylenes Caused by Trimethylsilyl and Trimethylgermyl Substituents
• Unusually High Reactivity of cis-Cp^*W(CO)_2(MeCN)Me to CO Insertion Reaction with Isocyanide
• An NMR Study of the Formation of N-Silylacetonitrilium Ions by Using Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as Counteranion1
• Siloxycarbenium Tetrakis[3,5-bis(trifluoromethyl)phenyl]borates and Their Role in Reactions of Ketones with Nucleophiles^
• Use of axially chiral 2'-methoxy-1,1'-binaphthyl-2-carboxylic acid as chiral derivatizing agent for discrimination of enantiomeric alcohols and amines by 1H NMR.
• On the mechanism of uncatalyzed reduction of triphenylmethyl chloride with triethylgermane.
• Preparation, characterization and stereochemistry of 2-methyl-2-silabicyclo(2.2.1)heptane derivatives.
• Stereochemistry of a chiral germyl radical in the reaction of carbon tetrachloride.
• Stereoselective cross-aldol reactions of silyl enol ethers with acetals catalyzed by iodotrimethylsilane.
• The Reaction of Hydrosilanes with Chlorosilanes in the Presence of Grignard Reagents. A New Method of Silicon-Silicon Bond Formation
• Relative Reactivities in the Addition of Free Trichloromethyl Radicals to Substituted Styrenes. An Attempt to Separate Polar and Resonance Effects

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