The Reaction of Hydrosilanes with Chlorosilanes in the Presence of Grignard Reagents. A New Method of Silicon-Silicon Bond Formation

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概要

• 論文の詳細を見る

• A new method has been developed for the formation of a silicon-silicon bond. Hydrosilanes having at least one phenyl or one trimethylsilyl group on a silicon atom were subjected to reaction with chlorosilanes to give unsymmetrically substituted disilanes in the presence of secondary or tertiary Grignard reagent which was inert to both chlorosilanes and hydrosilanes. The method was extended to the preparation of benzyl, allyl, and alkylsilanes.

• 公益社団法人 日本化学会の論文

著者

• Hosomi Akira

  Department Of Chemistry And Graduate School Of Chemistry University Of Tsukuba

• Sakurai Hideki

  Department Of Chemistiy Faculty Of Science Tohoku University

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