Convenient synthesis of .ALPHA.-mercaptoalkanoic acid esters using S-cyanomethyl thiocarbamates.

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概要

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• The reaction of cyanomethyl dithiocarbamate and <I>S</I>-cyanomethyl thiocarbamate with alkyl halides in aqueous medium selectively gave mono- and di-alkylated products. The treatment of the alkylated products with coned sulfuric acid gave α-mercaptoalkanoic acid esters.

• 公益社団法人 日本化学会の論文

著者

• Okawara Makoto

  Research Laboratory Of Resources Utilization Tokyo Institute Of Technology

• 増山 芳郎

  上智大学理工学部化学科

• Ueno Yoshio

  Research Institute For Biosciences And Department Of Toxicology And Microbial Chemistry Faculty Of Pharmaceutical Sciences Science University Of Tokyo

• Masuyama Yoshiro

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

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