Hexacarbonylmolybdenum(0)-catalyzed reaction of allylic carbonates with arylsulfonyl-stabilized carbanions.
スポンサーリンク
概要
- 論文の詳細を見る
<I>p</I>-Tolylsulfonylacetonitrile reacted with allylic carbonates in the presence of a catalytic amount of hexacarbonylmolybdenum(0) to give monoallylated derivatives. Using sodium hydride as a base, methyl <I>p</I>-tolylsulfonylacetate reacted with those to give mixtures of mono- and di-allylated derivatives. No nucleophilic attack of bulky bis-(phenylsulfonyl)methane occurred, whether sodium hydride was present or absent.
- 公益社団法人 日本化学会の論文
著者
-
増山 芳郎
上智大学理工学部化学科
-
Masuyama Yoshiro
Department Of Chemistry Faculty Of Sciecne And Technology Sophia University
-
Kurusu Yasuhiko
Department Of Chemistry Faculty Of Sciecne And Technology Sophia University
-
Hirai Hidenori
Department Of Biomedical Science Institute Of Regenerative Medicine And Biofunction Graduate School
-
Masuyama Yoshiro
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
-
Hirai Hidenori
Department of Chemistry, Faculty of Science and Technology, Sophia University
-
Segawa Koh-ichi
Department of Chemistry, Faculty of Science and Technology, Sophia University
関連論文
- Aldol-Type Reaction by Propen-2yl Acetate with NCS/SnCl_2/ROH
- 過酸およびヒドロペルオキシドを用いるエチレン - 1, 9-デカジエン共重合体のエポキシ化
- 過酸化水素水酸化によるモリブデン酸化物の活性化ならびにモリブデン過酸化物を用いる反応(予稿) (〔第49回〕触媒討論会特集号)
- π-アリルパラジウム錯体の見かけ上の電荷反転 : アリルアルコール類によるカルボニル-アリル化反応への応用
- Functional Characterization of the Recombinant Group II Chaperonin α from Thermoplasma acidophilum
- 2-Phenylthioallylation of Aldehydes with Allyl Phenyl Sulfides via Dibromination, Followed by Dehydrobromination
- Palladium-Catalyzed Allylic Amination of Allylic Alcohols with Tin(II) Chloride and Triethylamine
- In Turn or in Reverse Palladium-Catalyzed Carbonyl Allylation and Diels-Alder Reaction by 2-Methylene-3-buten-1-o1
- Tin(II) Iodide-catalyzed Selective Aziridination or 1,2-Diamination of Alkenes with Chloramine-T
- Temperature-programmed desorption of ammonia on zeolites. Influence of the experimental conditions on the acidity measurement.
- Convenient synthesis of .ALPHA.-mercaptoalkanoic acid esters using S-cyanomethyl thiocarbamates.
- Hexacarbonylmolybdenum(0)-induced dechalcogenization of allylic sulfides, sulfones, and selenides. Nucleophilic substitution and reductive dechalcogenization.
- Thermal behavior of a new type molybdenum oxide obtained by oxidation of molybdenum powder or molybdenum trioxide with hydrogen peroxide.
- Reductive Deacetoxylation of Allylic Acetates Using Hexacarbonylmolybdenum(0).
- Hexacarbonylmolybdenum(0)-catalyzed reaction of allylic carbonates with arylsulfonyl-stabilized carbanions.
- Catalytic epoxidation of cyclohexene with t-butyl hydroperoxide in the presence of various molybdenum complexes.
- Hexacarbonylmolybdenum(0)-catalyzed reductive coupling of allylic acetates.
- Titanium oxide-supported carbonylmolybdenum catalyst in liquid phase: Application to allylic alkylation of methyl p-tolylsulfonylacetate.
- Tetrabromooxomolybdate(V) complex. The catalytic reactivity for the reaction of t-butyl hydroperoxide.