Catalytic epoxidation of cyclohexene with t-butyl hydroperoxide in the presence of various molybdenum complexes.
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概要
- 論文の詳細を見る
A ligand can play an important role in the activity of the molybdenum-catalyzed epoxidation. Molybdenum complex was changed to the reactive intermediate through the reaction of catalyst with <I>t</I>-BuOOH. Oxalate, edta, and phenoxyl groups were selected as ligands. The phenoxyl group was most effective for the epoxidation. This effect was interpreted by the HSAB concept.
- 公益社団法人 日本化学会の論文
著者
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Yamazaki Masashi
Department Of Dermatology Juntendo University School Of Medicine
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Endo Hidetoshi
Department Of Comprehensive Geriatric Medicine National Center For Geriatrics And Gerontology
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Kurusu Yasuhiko
Department Of Chemistry Faculty Of Sciecne And Technology Sophia University
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Tomoyama Masato
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Endo Hidetoshi
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Yamazaki Masashi
Department of Chemistry, Faculty of Science and Technology, Sophia University
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