Tetrabromooxomolybdate(V) complex. The catalytic reactivity for the reaction of t-butyl hydroperoxide.

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概要

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• The nature of an ammonium counter cation of tetrabromooxomolybdate complex influences the rate of decomposition of <I>t</I>-butyl hydroperoxide(<I>t</I>-BuOOH) and oxidation with <I>t</I>-BuOOH. The catalytic activity of the ammonium for the decomposition of <I>t</I>-BuOOH decreased as the following order; benzyltrimethylammnium, –<I>N</I>-methyl pyridinium, –trimethylene bispyridinium, >>pyridinium, –quinolinium, >1,3-propanediammonium, −1,6-hexanediammonium. However, the reverse order was observed in the catalytic activity for the epoxidation by <I>t</I>-BuOOH, and the rate of oxidation of alcohol by <I>t</I>-BuOOH was independent of the nature of ammonium cation.

• 公益社団法人 日本化学会の論文

著者

• 増山 芳郎

  上智大学理工学部化学科

• Masuyama Yoshiro

  Department Of Chemistry Faculty Of Sciecne And Technology Sophia University

• Kurusu Yasuhiko

  Department Of Chemistry Faculty Of Sciecne And Technology Sophia University

• Masuyama Yoshiro

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

• Saita Mikio

  Department of Chemistry, Faculty of Sciencae and Technology, Sophia University

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