A new synthetic route to aliphatic and alicyclic nitriles via homolytic desulfurization of .ALPHA.-(dithiocarbamoylthio) nitriles.
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概要
- 論文の詳細を見る
Chloroacetonitrile was transformed into aliphatic and alicyclic nitriles through (dimethyldithiocarbamoylthio)acetonitrile. The key steps in the synthetic route consisted of mono- and dialkylation via sulfur-stabilized carbanion and homolytic desulfurization using tributyltin hydride.
- 公益社団法人 日本化学会の論文
著者
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Ueno Yoshio
Research Institute For Biosciences And Department Of Toxicology And Microbial Chemistry Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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Endo Takeshi
Research Laboratories, DENSO CORPORATION, Nisshin, Aichi 470-0111, Japan
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Watanabe Yoshihiko
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Yanagawa Makoto
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Moriya Osamu
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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