Synthesis of Blattellastanoside A, a Steroid Glucoside Isolated as the Aggregation Pheromone of the German Cockroach.
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概要
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β-Sitosterol (7) was converted to blattellastanoside A [5, 1-(6α-chloro-4β, 5β-epoxy-5β-stigmastan-3β-yl)-β-D-glucopyranoside], the structure proposed for the arrestant component of the aggregation pheromone of the German cockroach, Blattella germanica L. Our synthetic 5 was identical with the natural product on the basis of 1H and 13C NMR spectral comparison, HPLC analysis and pheromone activity.
- 日本学士院の論文
著者
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Mori Kenji
Department Of Agricultural Chemistry College Of Science And Technology The University Of Tokyo
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FUKAMATSU Kunio
Department of Agricultural Chemistry, The University of Tokyo
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