The rate of styrene and acrylonitrile copolymerization involving a minute amounts of either monomer.
スポンサーリンク
概要
- 論文の詳細を見る
In homogeneous radical copolymerization involving a minute amount of either monomer, the usual Mayo-Lewis type copolymerization rate equation might not be applicable to the consumption rate of the minor monomer component because of the penultimate effect. Precise data on the consumption rate of the minor monomer component are necessary to clarify this point. In this study, St-AN copolymerization involving a minor monomer was carried out to study the problem, using a continuous stirred-tank reactor under a wide range of experimental conditions. The above-mentioned aspect has been proved to hold in this copolymerization system. Considering the copolymer composition equation based on the penultimate effect, practical copolymerization rate equations were developed to cover the whole range of copolymerization, that is, up to the copolymerization at a minute concentration either of the monomers.
- 公益社団法人 化学工学会の論文
著者
-
HATATE Yasuo
Department of Applied Chemistry and Chemical Engineering
-
Nakashio Fumiyuki
Department Of Applied Chemistry Kyushu University
-
IKARI ATSUSHI
Department of Chemical Engineering, Faculty of Engineering, Kagoshima University
-
OTAKE TAKA-AKI
Department of Chemical Engineering, Faculty of Engineering, Kagoshima University
関連論文
- Electroselective Permeability Control of Microcapsule Immobilized Ferroelectric Liquid Crystals in an External Electrical Field
- Lactic Acid Bacteria-Enclosing Poly (ε-Caprolactone) Microcapsules as Soil Bioamendment(ENVIRONMENTAL BIOTECHNOLOGY)
- Characteristics of Solute Transfer in Sodium Dioleyl Phosphate/Sodium Bis(2-Ethylhexyl)Sulfosuccinate Microemulsion Systems
- Metal-Imprinted Microsphere Prepared by Surface Template Polymerization with W/O/W Emulsions
- Preparation and Release Characteristics of Biodegradable Microcapsules Encapsulating Activated Carbon Impregnated with Pesticide Using the Solvent Evaporation Method
- Extraction Equilibrium of Trivalent Erbium, Yttrium and Holmium with Dioleyl- and Dioctylphosphoric Acids
- Silver-mediated separation of polyunsaturated fatty acids by oil-in-water emulsion liquid membranes
- Liquid-Liquid Extraction of Metal Inos with a Cyclic Ligand Calixarene Carboxyl Derivative
- Solvent Extraction of Trivalent Rare Earth Metal Ions with Carboxylate Derivatives of Calixarenes
- DEVELOPMENT OF BI-FUNCTIONAL SURFACTANT FOR EXTRACTION OF PLATINUM WITH LIQUID SURFACTANT MEMBRANES
- Solvent Extraction Equilibria of Rare Earth Metals by Acidic Organophosphorus Extractants with Bulky Substituents
- SELECTIVE SEPARATION OF RARE EARTH METALS WITH NEW OIL-SOLUBLE COMPLEXING AGENTS
- Entrapment Efficiency of Inorganic Salts into Biodegradable Microcapsules Prepared by the Solvent Evaporation Method
- リノレン酸メチルの自動酸化中におけるトリプシン阻害および促進物質の同時発現--トリプシン阻害物質の確認
- Electro-Sensitive Microcapsule Immobilized Ferroelectric Liquid Crystal
- Improvement of Fluidized State of Geldart's A-Type Particles with Smooth Surface by Ultra-Fine Powder Addition
- Catalytic decomposition of hydrocarbon into hydrogen and carbon in a spouted-bed reactor as the second-stage reactor of a plastic recycling process
- Formation of Carbon and Hydrogen from Lower Hydrocarbons in a Packed Bed of Nickel-plated Alumina Balls
- Flash-Pyrolyzed Product Distribution of Major Plastics in a Batch Reactor
- Characteristics of Flow Behavior in Semi-Cylindrical Spouted Bed with Draft Tube
- Application of High-Velocity Fluidized Bed Reactor for Producing Hollow Inorganic Microspheres from Volcanic Glass Particles
- VAPOL-LIQUID EQUILIBRIA OF MINUTE AMOUNTS OF N-METHYLSSUCCINIMIDE AND WATER IN N-METHYL-2-PYRROLIDONE
- Preparation of Cross-Linked Microcapsules Entrapping Inorganic Salt by In-situ Polymerization in (W/O/W) Emulsion System
- Production of Ethanol from Distilled Shochu Mash through Saccharification by a Cellulase and Fermentation by a Saccharomyces cerevisiae : study for Basic Experimental Conditions of Saccharification
- Association Behavior of Singly Chain-End Hydrophobically-Modified Poly(vinyl alcohol) in Aqueous Solution
- Characteristics of Biodegradable Microcapsules by Solvent Evaporation in (W/O/W) Emulsion System
- NOVEL PROCEDURE FOR MONODISPERSED POLYMERIC MICROSPHERES WITH HIGH ELECTRIFYING ADDITIVE CONTENT BY PARTICLE-SHRINKING METHOD VIA SPG MEMBRANE EMULSIFICATION
- PERMEABILITY CONTROL OF ACTIVE AGENT FROM POLYMERIC MICROCAPSULES BY COATING OF GELATIN/GUM ARABIC MEMBRANE
- PREPARATION OF DIVINYLBENZENE HOMOPOLYMERIC MICROCAPSULES WITH HIGHLY POROUS MEMBRANES BY IN SITU POLYMERIZATION WITH SOLVENT EVAPORATION
- pH-SENSITIVE RELEASE FROM POLY(ACRYLAMIDE-CO-N, N'-METHYLENE BISACRYLAMIDE)MICROSPHERES
- METAL ION-IMPRINTED RESINS WITH NOVEL BIFUNCTIONAL MONOMER BY SURFACE TEMPLATE POLYMERIZATION
- NOVEL METAL ION-IMPRINTED RESINS PREPARED BY SURFACE TEMPLATE POLYMERIZATION WITH W/O EMULSION
- Surfactant-Chymotrypsin Complex as a Novel Biocatalyst in Organic Media
- Effect of Using a Co-Solvent in the Preparation of Surfactant-Coated Lipases on Catalytic Activity in Organic Media
- NOVEL IMMOBILIZED ENZYMES UTILIZING REVERSED MICELLAR SOLUTIONS AS AN OPTICAL RESOLUTION TOOL
- Important Factors Affecting Enzymatic Functions of PEG Microspheres Containing Lipase Complexes
- Mono-core Coating of Fine Particles with Finer Particles by Means of a Draft-Tube Spouted-Bed with Medium Particles
- ELECTROSTATIC PROPERTIES OF POLY (STYRENE-CO-DIVINYLBENZENE) MICROSPHERES WITH DIFFERENT SURFACE MORPHOLOGIES
- ELECTROSTATIC CHARACTERIZATION OF POLYMERIC MICROSPHERES CONTAINING ELECTRIFYING ADDITIVES
- CONTROLLED RELEASE OF STYRENE-DIVINYLBENZENE COPOLYMER MICROCAPSULES BY PHASE TRANSFORMATION OF ENCAPSULATED STEARIC ACID
- REGENERATION OF STYRENE-DIVINYLBENZENE COPOLYMER MICROCAPSULES CONTAINING TRI-N-OCTYL AMINE
- PREPARATUON AND EXTRACTION PROPERTIES OF MICROCAPSULES CONTAINING TRI-N-OCTYL AS CORE MATERIAL AMINE
- DESIGN OF SURFACTANTS SUITABLE FOR SURFACTANT-COATED ENZYMES AS CATALYSTS IN ORGANIC MEDIA
- Surfactant-Lipase Complexes Immobilized in PEG Microspheres
- Coating of Particles with Finer Particles Using a Draft-Tube Spouted-Bed
- Multi-layered Gelatin/Acacia Microcapsules by Complex Coacervation Method.
- Lactic Acid Bacteria-Enclosing Poly(ε-Caprolactone) Microcapsules as Soil Bioamendment
- Gas holdup and pressure drop in three-phase horizontal flows of gas-liquid-fine solid particles system.
- Behavior of bubbles in a semi-cylindrical gas-solid fluidized bed.
- Heat transfer coefficient in three-phase vertical downflows of gas-liquid-fine solid particles system.
- Extraction Equilibria of Amino Acids with Quaternary Ammonium Salt
- Behavior of bubbles in a cylindrical fluidized bed at an elevated temperature.
- Effect of bed temperature on bubble size and bubble rising velocity in a semi-cylindrical slugging fluidized bed.
- Extraction equilibrium of hydrochloric acid with tri-n-octylamine.
- Acceleration effect of anionic surfactants on extraction rate of copper with liquid surfactant membrane containing LIX65N and nonionic surfactant.
- Copper extraction with liquid surfactant membrane in Mixco extractor.
- Extraction equilibria of Cu(II), Zn(II) and Co(II) with N-8-quinolylsulfonamides.
- Extraction of copper with liquid surfactant membranes containing benzoylacetone.
- Extraction equilibria of copper and zinc with alkylphosphonic acid monoester.
- Vapor-Liquid Equilibria of a Minute Amount of Furfural in Water-Ethanol-1-Propanol System.
- Suspension polymerization of styrene under ultrasonic irradiation.
- A simulation of continuous suspension polymerization of styrene by the Monte Carlo method.
- Styrene slurry polymerization within suspended droplets in a continuous stirred tank reactor.
- Change of size distribution of polymer droplets during the slurry polymerization of styrene within isooctane droplets suspended in water.
- Solvent extraction of copper by benzoylacetone in a stirred transfer cell.
- Formation of nickel concentration profile in nickel/alumina catalyst during post-impregnation drying.
- BEHAVIOR OF VARIOUS IMPURITIES IN SIMPLE DISTILLATION OF AQUEOUS SOLUTION OF ETHANOL
- The rate of styrene and acrylonitrile copolymerization involving a minute amounts of either monomer.
- Kinetics of styrene slurry polymerization in suspended isooctane droplets.
- Kinetics of copper extraction with N-8-quinolyl-p-dodecylbenzenesulfonamide.
- Extraction equilibria of copper and zinc with N-8-quinolylsulfonamides.
- Effect of hydrophobicity of extractant on extraction kinetics of copper with N-8-quinolylsulfonamide.
- EFFECT OF ULTRASONIC WAVES ON BULK POLYMERIZATION OF STYRENE
- STYRENE AND ACRYLONITRILE COPOLYMERIZA-TION UNDER ULTRASONIC IRRADIATION
- Effect of nickel concentration profile on selectivity of acetylene hydrogenation.
- Kinetics of stripping of N-8-quinolyl-p-dodecylbenzenesulfonamide-copper chelate complex with hydrochloric acid.
- Effects of nickel source material on characteristics of nickel/alumina impregnated catalysts.
- Effects of post-impregnation drying conditions on physical properties and overall reaction rate of nickel/alumina catalysts.
- Effects of viscosity on drop diameter of W/O emulsion dispersed in a stirred tank.
- Electrical demulsification of W/O emulsion by continuous tubular coalescer.
- Catalytic effect of bisoleylphosphoric acid on copper extraction with N-8-quinolylsulfonamide.
- Protein extraction by reversed micelles using dioleyl phosphoric acid.
- Development of new surfactant for liquid surfactant membrane process.
- Development of amphoteric surfactant for liquid surfactant membrane in metal extraction process.
- Extraction kinetics of copper with liquid surfactant membranes in a stirred transfer cell.
- Selection of break-up tracer for evaluation of stability of liquid surfactant membrane.
- Characterization of supported nickel catalysts prepared by deposition of nickel chloride vapor on alumina.