EFFECT OF ULTRASONIC WAVES ON BULK POLYMERIZATION OF STYRENE
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概要
- 論文の詳細を見る
The bulk polymerization of styrene was carried out under ultrasonic irradiation. The effects of power input and frequency of ultrasonic waves on the polymerization rate and the molecular weight distribution of polymer were studied. The mechanism of polymerization was not affected by ultrasound, but the overall rate constant decreased linearly with increase of net ultrasonic energy, and the average molecular weight of polymer slightly increased with ultrasonic irradiation. These results are caused by the accelaration of termination reaction and/or the decrease of initiator efficiency with ultrasonic irradiation.
- 公益社団法人 化学工学会の論文
著者
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Miyata Takao
Department Of Earth And Planetary Sciences Faculty Of Science Kobe University
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Nakashio Fumiyuki
Department Of Applied Chemistry Kyushu University
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MIYATA TAKAO
Department of Organic Synthesis, Faculty of Engineering, Kyushu University
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