Kinetics of absorption of nitric oxide in aqueous acidic solutions of ferrous sulfate.
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概要
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The rates of absorption of nitric oxide in aqueous acidic solutions of ferrous sulfate of concentrations ranging from 0.0625 to 0.5 g-mol/l were measured at 15, 25 and 35°C using a liquid-jet column and a wetted-wall column. The experimental results were analysed with the chemical absorption theory based on the penetration model. The second-order forward rate constants for the reaction between nitric oxide and ferrous sulfate in aqueous solutions were calculated and correlated as a function of temperature and ionic strength of the solution. The chemical equilibrium constants for the reaction were also determined from the measurements of the total solubility of nitric oxide in aqueous ferrous sulfate solutions.
- 公益社団法人 化学工学会の論文
著者
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Asai Satoru
Department Of Chemical Engineering University Of Osaka
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Ishikawa Haruo
Department Of Chemical Engineering Graduate School Of Engineering Osaka Prefecture University
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Hikita Haruo
Department of Chemical Engineering, University of Osaka Prefecture
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HIRANO SHIGEYUKI
Department of Chemical Engineering, University of Osaka Prefecture
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