Kinetics of absorption of no into aqueous Na2SO3 solutions containing Fe(III)-EDTA-Na and Fe2(SO4)3.
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概要
- 論文の詳細を見る
The rates of absorption of NO into aqueous Na2SO3 solutions containing Fe(III)-EDTA-Na and/or Fe2(SO4)3 as catalysts were measured at temperatures from 8 to 45°C using a baffled agitated vessel with a flat gas-liquid interface. The experimental results were analyzed by chemical absorption theory and it was found that the reaction is first-order with respect to NO and zeroorder with respect to Na2SO3 for solutions containing Fe(III)-EDTA-Na alone or both Fe(III)-EDTA-Na and Fe2(SO4)3. The first-order rate constants for both catalyzed solutions were calculated and correlated as functions of temperature, ionic strength of the solution and concentrations of Fe(III)-EDTA-Na and Fe2(SO4)3.
- 公益社団法人 化学工学会の論文
著者
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Asai Satoru
Department Of Chemical Engineering University Of Osaka
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Ishikawa Haruo
Department Of Chemical Engineering Graduate School Of Engineering Osaka Prefecture University
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Okamoto Takashi
Department Of Agricultural Chemistry Faculty Of Agriculture Kinki University
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Hikita Haruo
Department of Chemical Engineering, University of Osaka Prefecture
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SAKAMOTO SHIZUO
Kurimoto Iron Works, Ltd.
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KITAGAWA MASAFUMI
Kurimoto Iron Works, Ltd.
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