Aromatic Annelation with α-PhenyIsulfinyl-γ-butyrolactones. A Novel Route to 4-(2-Hydroxyalkyl)-1,3-benzenediols(Organic,Chemical)
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概要
- 論文の詳細を見る
A number of 4-(2-hydroxyalkyl)-1,3-benzenediols (4) were synthesized by thermolysis of 1,3-cyclohexadiones (3), which were obtained by the reaction of α-phenylsulfiyl-γ-butyrolaetones (1) with α,β-unsaturatcd ketones (2), providing a new aromatic annelation. One of the compounds thus obtained, 4-(3,4-dihydro-4-hydroxy-7-methoxy-2H-1-benzopyran-3-yl)-1,3-benzenediol (4n), was converted to isomedicarpin (5b) and hornopterocarpin (5c).
- 社団法人日本薬学会の論文
- 1987-05-25
著者
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尾崎 裕
城西大学薬学部
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尾崎 裕
Faculty Of Pharmaceutical Sciences Osaka University
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金 相元
城西大学薬学部
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持田 佳以子
Faculty of Pharmaceutical Sciences, Josai University
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Ozaki Y
Division Of Pharmacognosy And Phytochemistry National Institute Of Health Sciences
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Ozaki Y
National Inst. Health Sci. Tokyo Jpn
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持田 佳以子
Faculty Of Pharmaceutical Sciences Josai University
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