X-Ray Cl L_<2,3> Spectra and Electronic Structures of Transition-Metal Dichlorides
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概要
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The valence-band structures of transition-metal dichlorides were studied using the X-ray spectroscopic technique. The Cl L_<2,3> emission band spectra of the valence band of Fe-, Co-and Ni-dichlorides were measured and compared with the valence-band XPS spectra and the Cl L_<2,3> absorption spectra. The peaks located around 192 and 196 eV in the Cl L_<2,3> emission band spectra are attributed to the p band and the d band which mainly originate from the Cl 3p state and the transition-metal 3d state, respectively. These spectra seem to reflect the energyband structure and suggest that the unpaired 3d-electrons of transition-metal compounds scarcely affect the inner core 2p hole of Cl^- ion.
- 社団法人応用物理学会の論文
- 1981-11-05
著者
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Nakamura Hatsuo
Faculty Of Engineering Osaka Electro-communication University
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Ichikawa Kouichi
College Of Engineering Osaka Prefecture University
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