Studies on Organic Sulfur Compounds. XIV. The Reaction of N-Alkoxy-carbonyl-N'-(2-thiazolyl) thioureas with Some Oxidants
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概要
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N-Alkoxycarbonyl-N'-(2-thiazolyl) thioureas were reacted with some oxidants, such as bromine, benzoyl peroxide, hypobromous acid and N-bromosuccinimide, to afford 2-alkoxycarbonylimino-thiazolo [3,2-b] thiadiazolines (X). Furthermore, from the reaction mixtures of N-ethoxycarbonyl-N'-(2-thiazolyl) thiourea (12) with bromine in chloroform, N-ethoxycarbonylimino-thiazolo [3,2-b] thiadiazoline hydrobromide monohydrate (14) was obtained, which was easily dehydrobrominated to form 2-ethoxycarbonylimino-thiazolo-[3,2-b] thiadiazoline (13) by treatment with large quantities of water. This paper describes particularly in detail about the structures of 13 and 14.
- 公益社団法人日本薬学会の論文
- 1973-11-25
著者
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長野 光男
Central Research Laboratories, Sankyo Co., Ltd.
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松井 孝
Agricultural Chemical Research Laboratories Sankyo Co. Ltd.
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松井 孝司
三共・農薬研
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飛塚 淳三
三共・農薬研
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大重 みち子
Central Research Laboratories And Agricultural Chemical Research Laboratories Sankyo Co. Ltd.
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木下 孝
Central Research Laboratories and Agricultural Chemical Research Laboratories, Sankyo Co., Ltd.
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松井 孝司
Central Research Laboratories and Agricultural Chemical Research Laboratories, Sankyo Co., Ltd.
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飛塚 淳三
Central Research Laboratories and Agricultural Chemical Research Laboratories, Sankyo Co., Ltd.
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小山田 浩三
Central Research Laboratories and Agricultural Chemical Research Laboratories, Sankyo Co., Ltd.
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長野 光男
Central Research Laboratories Sankyo Co. Ltd.
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小山田 浩三
三共・農薬研:(現)東大阪短大
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木下 孝
Central Research Laboratories And Agricultural Chemical Research Laboratories Sankyo Co. Ltd.
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大重 みち子
Central Research Laboratories
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