Studies on the Erythrina Alkaloids. VIII. Alkaloids of Erythrina X bidwillii LINDL. (4). Synthesis of Erybidine by Photochemical Reaction
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概要
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Irradiation of methanolic solution of amide (VIII) by a 100 W high pressure mercury lamp in the presence of sodium hydroxide afforded a mixture of three phenolic irradiation products, whose structures were proved to be IX, X and XI respectively on the basis of chemical and spectral studies. Among these photocyclization products, X was reducted with sodium borohydride and boron trifluoride to provide the amine (XIII), which was converted with formalin and sodium borohydride to erybidine (I).
- 公益社団法人日本薬学会の論文
- 1974-09-25
著者
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田中 斉
Faculty Of Pharmacy Meijo University
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伊藤 一男
Faculty of Pharmacy, Meijo University
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伊藤 一男
Faculty Of Pharmacy Meijo University
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