Total Synthesis of Cleomiscosin A, a Coumarinolignoid
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概要
- 論文の詳細を見る
The coumarinolignoid cleomiscosin A (1), having antitumor activity, has been synthesized via the keto-ester (10), which was prepared from readily available starting materials (6 and 9). Removal of the methoxymethyl group of 10 followed by reduction with lithium borohydride gave a mixture of diols (12a, b). Treatment of 12a, b with 5% sulfuric acid in acetic acid provided cleomiscosin A monoacetate (14) and subsequent hydrolysis with sodium hydroxide afforded 1.
- 社団法人日本薬学会の論文
- 1985-08-25
著者
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田中 斉
Faculty Of Pharmacy Meijo University
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伊藤 一男
Faculty of Pharmacy, Meijo University
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加藤 一郎
Faculty of Pharmacy, Meijo University
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伊藤 一男
Faculty Of Pharmacy Meijo University
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加藤 一郎
Faculty Of Pharmacy Meijo University
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