Structures of Prosapogenin-B and -A of Dioscin and Cooccurrence of B with Dioscin in the Rhizoma of Dioscorea Tokoro MAKINO
スポンサーリンク
概要
- 論文の詳細を見る
Prosapogenins, B and A, which are provided together with prosapogenin-C (diosgenin β-D-glucopyranoside) (II) on partial hydrolysis of dioscin (diosgenin 2-O- and 4-O-bis-α-L-rhamnopyranosyl-β-D-glucopyranoside=diosgenin β-chacotrioside) (I) were characterized as 4-O-(III) and 2-O-α-L-rhamnopyranosyl-β-D-glucopyranoside (IV), respectively. A glycoside found along with dioscin, gracillin and other spirostanol glycosides in the rhizoma of Dioscorea Tokoro MAKINO was isolated and identified with prosapogenin-B of dioscin on the basis of paper, thin-layer and, for the first time, gas liquid chromatographic comparisons and chemical evidence. The difference of the site of the probable enzymatic cleavage in the sugar portion (chacotriose) of dioscin from that of the splitting by acid hydrolysis was noted.
- 公益社団法人日本薬学会の論文
- 1968-06-25
著者
-
川崎 敏男
Faculty of Pharmaceutical Sciences of Kyushu University
-
川崎 敏男
Faculty Of Pharmaceutical Sciences Kyushu University
-
山内 辰郎
Faculty of Pharmaceutical Sciences, Fukuoka University
-
山内 辰郎
Faculty Of Pharmaceutical Sciences Fukuoka University
関連論文
- 大麻に関する研究(第4報) : 喫煙試験
- Steroid Saponins from Paris polyphylla SM.-Supplement
- Resin Glycosides. XIII. Operculins VI, XI, XII, XIII, XIV and XV, the Ehter-Soluble Resin Glycosides (Jalapin) from Rhizoma Jalapae Braziliensis (Roots of Ipomoea operculata)
- Steroid Saponins and Sapogenins of Underground Parts of Trillium kamtschaticum PALL. IV. Additional Oligoglycosides of 18-Norspirostane Derivatives and Other Steroidal Constituents
- Cinncassiol C_1,a Novel Type of Diterpene from Cinnamomi Cortex
- Steroid Saponins and Sapogenins of Underground Parts of Trillium kamtschaticum PALL. III. On the Structure of a Novel Type of Steroid Glycoside, Trillenoside A, an 18-Norspirostanol Oligoside
- Steroid Saponins of Aerial Parts of Paris tetraphylla A. GRAY and of Underground Parts of Trillium tschonoskii MAXIM.
- Steroid Saponins of Heloniopsis orientalis (THUNB.) C. TANAKA
- Steroid Saponins and Sapogenins of Underground Parts of Trillium kamtschaticum PALL. II. Pennogenin- and Kryptogenin 3-O-Glycosides and Related Compounds
- Steroid Glycosides in Paris polyphylla SM.
- Detection of Proto-type Compounds of Diosgenin-and Other Spirostanol-Glycosides
- A NOVEL RESIN GLYCOSIDE, MERREMIN (TUGUAJALAPIN X DIMER), FROM MERREMIA HUNGAIENSIS
- Three Glycosphingolipids Having the Phosphocholine Group from the Crude Drug "Jiryu" (The Earthworm, Pheretima asiatica)
- Resin Glycosides. XVIII. Determination by Mosher's Method of the Absolute Configurations of Mono- and Dihydroxyfatty Acids Originated from Resin Glycosides
- Resin Glycosides. VII. : Reinvestigation of the Component Organic and Glycosidic Acids of Pharbitin, the Crude Ether-Insoluble Resin Glycoside ("Convolvulin") of Pharbitidis Semen (Seeds of Pharbitis nil)
- Resin Glycosides. IV. Two New Resin Glycosides, Muricatins VII and VIII : from the Seeds of Ipomoea muricata
- Resin Clycosides. III : Isolation and Structural Study of the Genuine Resion Glycosides, Muricatins I : VI, from the Seeds of I pomoea muricata
- Resin Glycosides. II. : Identification and Characterization of the Component Organic and Glycosidic Acids of the Crude Resin Glycoside from the Seeds of Ipomoea muricata
- The X-Ray Analysis of Caesalpin J from Sappan Lignum
- The Constituents of Paris verticillata M. v. BIEB.
- Studies on the Constituents of Momordica cochinchinensis SPRENG. I. Isolation and Characterization of the Seed Saponins, Momordica Sapponins I and II
- Amides from Huajiao, Pericarps of Zanthoxylum bungeanum MAXIM.
- Studies on the Constituents of Actinostemma lobatum MAXIM. V. : Structures of Lobatosides B, E, F and G, the Dicrotalic Acid Esters of Bayogenin Bisdesmosides Isolated from the Herb
- Studies on the Constituents of Actinostemma lobatum MAXIM. IV. Structures of Lobatosides C, D and H, the Dicrotalic Acid Esters of Bayogenin Bisdesmosides Isolated from the Herb
- Studies on the Constituents of Actinostemma lobatum MAXIM. III. : Structures of Actinostemmosides E and F, New Baccharane-Type Triterpene Glycosides Isolated from the Herb
- Studies on the Constituents of Actinostemma lobatum MAXIM. I. Structures of Actinostemmosides A, B, C and D, Dammarane Triterpene Glycosides Isolated from the Herb(Organic,Chemical)
- Minor Cardenolide Glycosides and a Cardenolide from the Leaves of Anodendron affine (Anodendron. VIII)
- Studies on the Constituents of Thladiantha dubia BUNGE. I. : The Structures of Dubiosides A, B and C, the Quillaic Acid Glucuronide Saponins Isolated from the Tuber
- Neridienone A, a C_-Steroid in Nerium odorum
- Inhibitors of Angiotensin-Converting Enzyme in Crude Drugs. II
- Inhibitors of Angiotensin Converting Enzyme in Crude Drugs. I
- Kikuba-saponin. (1). (Saponins of Japanese Dioscoreaceae. X.)
- Studies on the Constituents of Aster tataricus L. f. IV. : Structures of Aster Saponins Isolated from the Herb
- Resin Glycosides. XV. Simonins I-V, Ether-Soluble Resin Glycosides (Jalapins) from the Roots of Ipomoea batatas (cv. Simon)
- Digitalis Saponins. III. Enzymatic Hydrolysis of Leaf Saponins of Digitalis purpurea L.
- Digitalis Saponins. II. Leaf Saponins of Digitalis purpurea L.
- Digitalis Saponins. I. Seed Saponins of Digitalis purpurea L. (Commercial "Digitonin")
- ジギタリスプルプレア葉サポニンの構造
- Studies on the Agalwood (Jinko). VIII. : Structures of Bi-phenylethylchromone Derivatives
- Studies on the Constituents of Momordica charantia L. I. Isolation and Characterization of Momordicosides A and B, Glycosides of a Pentahydroxy-cucurbitane Triterpene
- Pericarp Saponins of Akebia quinata DECNE. II. Arjunolic and Norarjunolic Acids, and Their Glycosides
- Pericarp Saponins of Akebia quinata DECNE. I. Glycosides of Hederagenin and Oleanolic Acid
- Dehydro-para-asebotin, a New Chalcone Glucoside in the Flowers of Gnaphalium affine D. DON
- A New Diosgenin Glycoside, Aspidistrin, from Aspidistra elatior BLUME
- Seed Saponins of Akebia quinata DECNE. II. Hederagenin 3,28-O-Bisglycosides
- Studies on Resin Glycosides. III. Complete Structures of Pharbitic Acids C and D
- Studies on Resin Glycosides. II. Unhomogeneity of "Pharbitic Acid" and Isolation and Partial Structures of Pharbitic Acids C and D, the Major Constituents of "Pharbitic Acid"
- Studies on Resin Glycosides. I. Reinvestigation of the Components of Pharbitin, a Resin Glycoside of the Seeds of Pharbitis Nil CHOISY
- A New Xanthone C-Glucoside, Position Isomer of Mangiferin, from Anemarrhena asphodeloides BUNGE
- A Mangiferin Monomethyl Ether from Mangifera indica L.
- Partial Methylation with Diazomethane of the Sugar Moiety of Some C- and O-D-Glucopyranosides
- Isolation and Identification of Swertisin from the Leaves of Desmodium caudatum A.P. de CANDOLLE
- Octa (Per)-, Hepta- and Mono-Acetates of Dioscin
- Structures of Prosapogenin-B and -A of Dioscin and Cooccurrence of B with Dioscin in the Rhizoma of Dioscorea Tokoro MAKINO
- A Mangiferin Monomethyl Ether from Mangifera indica L.
- Saponins of Timo (知母 : Anemarrhenae Rhizoma). II. Structure of Timosaponin A-III.
- Reduction of 1-Methyl-3-and-4-methoxycarbonyl Pyridinium Iodide with Sodium Borohydride
- Structures of Dioscin, Gracillin, and Kikuba-saponin. (2). (Saponins of Japanese Dioscoreaceae. XI.)
- Resin Glycosides. XIX. Woodrosins I and II, Ether-Insoluble Resin Glycosides from the Stems of Ipomoea tuberosa
- Resin Glycosides. XVI. Marubajalapins I-VII, New Ether-Soluble Resin Glycosides from Pharbitis purpurea
- Resin Glycosides XIV. Quamoclins I-IV, New Ether-Soluble Resin Glycosides (Jalapin) from the Seeds of Quamoclit pennata
- Resin Glycosides. XI. Operculins III, IV, IX, X, XVI, XVII and XVIII, New Ether-Soluble Resin Glycosides of Rhizoma Jalapae Braziliensis (Root of Ipomoea operculata)
- Resin Glycosides. IX. : Operculins I, II, V, VII and VIII, New Ether-Soluble Resin Glycosides of Rhizoma Jalapae Braziliensis(the Roots of Ipomoea operculata)
- Resin Glycosides. VIII. : Four New Glycosidic Acids, Operculinic Acids D, E, F, and G, of the Ether-Soluble Crude Resin Glycosides ("Jalapin") from Rhizoma Jalapae Braziliensis (Roots of Ipomoea operculata)
- Resin Glycosides. V. : Identification and Characterization of the Component Organic and Glycosidic Acids of the Ether-Soluble Crude Resin Glycosides ("Jalapin") from Rhizoma Jalapae Braziliensis (Roots of Ipomoea Operculata)
- THE STRUCTURE OF AH_, NEW TETRAHYDROXY-2-(2-PHENYLETHYL)CHROMONE FROM AGALWOOD
- OPERCULIN I AND II, NEW ETHER-SOLUBLE RESIN GLYCOSIDES ("JALAPIN") WITH FATTY ACID ESTER GROUPS FROM RHIZOMA JALAPAE BRAZILIENSIS (ROOTS OF& IPOMOEA OPERCULATA)
- Studies on the Agalwood (Jinko). VII. : Structures of Phenylethyl-chromone Derivatives AH_7,AH_8 and AH_9
- Parsonsianine, a Macrocyclic Pyrrolizidine Alkaloid from the Leaves of Parsonsia laevigata (Studies on Parsonsia, III)
- Studies on the Constituents of Aster tataricus L. f. III. : Structures of Aster Saponins E and F Isolated from the Root
- Furanoid Norditerpenes from Dioscorea Plants. VII. Structures of Diosbulbinosides D and F
- Strophanthidin Glycosides from the Roots of Apocynum venetum var. : basikurumon : Studies on Apocynum. II
- Pregnanes and Pregnane Glycosides from the Roots of Apocynum venetum var. basikurumon : Apocynum. I(Organic,Chemical)
- Conversion of Steroid Saponins to the Corresponding Pregnane Glycosides
- Cannabichromenic Acid, a Genuine Substance of Cannabichromene
- Studies on the Plant Sterols and Triterpenes. II. Separation of Stigmasterol, β-Sitosterol and Campesterol, and about So-called "γ-Sitosterol."
- CHARACTERIZATION OF A MINOR COMPOUND, WHICH ACCOMPANIES THE USUAL 22α (R)-0,25β (S)-SPIROSTANOL GLYCOSIDE, AS A NOVEL TYPE OF 22β (S)-0,25α (S) ANALOG
- CO-OCCURRENCE AND HIGH-PERFORMANCE LIQUID CHROMATOGRAPHIC SEPARATION OF THE GLYCOSIDES OF RHODEASAPOGENIN AND ITS ANALOGS WHICH DIFFER IN THE F-RING STRUCTURE
- Studies on the Constituents of Mallotus japonicus MUELL. ARG. I. Cardiac Glycosides from the Seeds
- Studies on the Constituents of the Crude Drug "Fritillariae Bulbus." III. On the Diterpenoid Constituents of Fresh Bulbs of Fritillaria thunbergii MIQ.
- Furanoid Norditerpenes from Dioscoreaceae Plants. I. Diosbulbins A, B and C from Dioscorea bulbifera L. forma spontanea MAKINO et NEMOTO
- Iridoids from the Roots of Thevetia peruviana
- Cardenolide Glycosides from the Roots of Apocynum cannabinum
- Steroidal Constituents from the Roots and Stems of Asclepias fruiticosa
- Cardenolide Glycosides from the Seeds of Asclepias curassavica
- Oxygenated Anodendrosins from the Seeds of Anodendron affine(Studies on Anodendron. XI)
- Anodendrosins J and K, Two Sucrose Bisglycosylnervogenates from the Seeds of Anodendron affine Studies on Anodendron. IX
- 3'-epi-19-Norafraside and 12β-Hydroxycoroglaucigenin from Asclepias curassavica
- Pyrrolizidine Alkaloids from Parsonsia laevigata in Okinawa Island (Studies on Parsonsia. V)
- Tanegosides A, B and C, Lignan Glycosides from Trachelospermum liukiuense
- Alschomine and Isoalschomine, New Alkaloids from the Leaves of Alstonia scholaris
- Isolation of ⊿^-Desoxytigogenin (25D-Spirosta-3,5-diene) from some Dioscoreaceae Plants
- Studies on the Constituents of the Stems of Tinospora tuberculata BEUMEE. II. New Diterpenoids, Borapetoside A and Borapetol A
- Cannabigerol Monomethyl Ether, a New Component of Hemp
- NOVEL BI-ISOFLAVONOIDS FROM DALBERGIA ODORIFERA
- Seed Saponins of Akebia quinata DECNE I. Hederagenin 3-O-Glycosides
- OLIGOGLYCOSIDES OF SPIROCYCLIC NORTRITERPENOIDS RELATED TO EUCOSTEROL
- A New Spirostanol, 19-Hydroxyyonogenin, from the Aerial Parts of Dioscorea tokoro MAKINO
- Studies on the Constituents of the Aerial Parts of Dioscorea tenuipes FRANCH. et SAVAT. IV. 2β, 3α, 4β-Trihydroxy-5β-pregn-16-en-20-one and Its 2- and 4-Monoacetates
- Isolation and Structure of a New Tokorogenin Glycoside