Seed Saponins of Akebia quinata DECNE. II. Hederagenin 3,28-O-Bisglycosides
スポンサーリンク
概要
- 論文の詳細を見る
The more polar four triterpenoid saponins, D-G, of the seven, A-G, so far isolated in pure state from the seeds of Akebia quinata DECNE. were characterized as follows : saponin D (mp>225°(decomp.), [α]_D+15°), 3-O-α-L-arabinopyranosyl hederagenin 28-O-β-D-glucopyranosyl-(1→6)-β-D-glucopyranoside (IV) ; E (mp 210-214°(decomp.), [α]_D+6°), 3-O-β-D-xylopyranosyl-(1→2)-α-L-arabinopyranosyl hederagenin 28-O-β-D-glucopyranosyl-(1→6)-β-D-glucopyranoside (XI) ; F (mp 211-214°(decomp.), [α]_D-4°), 3-O-β-D-glucopyranosyl-(1→2)-α-L-arabinopyranosyl hederagenin 28-O-β-D-glucopyranosyl-(1→6)-β-D-glucopyranoside (XIV) ; G (mp>218°(decomp.), [α]_D-19°), 3-O-β-D-glucopyranosyl-(1→2)-[α-L-rhamnopyranosyl-(1→4)]-α-L-arabinopyranosyl hederagenin 28-O-α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→6)-β-D-glucopyranoside (XVI). They are new hederagenin 3,28-O-bisglycosides and related to each other and to saponins A, B, and C.
- 公益社団法人日本薬学会の論文
- 1972-10-25
著者
-
川崎 敏男
Faculty of Pharmaceutical Sciences of Kyushu University
-
川崎 敏男
Faculty Of Pharmaceutical Sciences Kyushu University
-
樋口 隆一
Faculty of Pharmaceutical Sciences, Kyushu University
-
樋口 隆一
Faculty Of Pharmaceutical Sciences Kyushu University
関連論文
- Steroid Saponins from Paris polyphylla SM.-Supplement
- Resin Glycosides. XIII. Operculins VI, XI, XII, XIII, XIV and XV, the Ehter-Soluble Resin Glycosides (Jalapin) from Rhizoma Jalapae Braziliensis (Roots of Ipomoea operculata)
- Steroid Saponins and Sapogenins of Underground Parts of Trillium kamtschaticum PALL. IV. Additional Oligoglycosides of 18-Norspirostane Derivatives and Other Steroidal Constituents
- Cinncassiol C_1,a Novel Type of Diterpene from Cinnamomi Cortex
- Steroid Saponins and Sapogenins of Underground Parts of Trillium kamtschaticum PALL. III. On the Structure of a Novel Type of Steroid Glycoside, Trillenoside A, an 18-Norspirostanol Oligoside
- Steroid Saponins of Aerial Parts of Paris tetraphylla A. GRAY and of Underground Parts of Trillium tschonoskii MAXIM.
- Steroid Saponins of Heloniopsis orientalis (THUNB.) C. TANAKA
- Steroid Saponins and Sapogenins of Underground Parts of Trillium kamtschaticum PALL. II. Pennogenin- and Kryptogenin 3-O-Glycosides and Related Compounds
- Steroid Glycosides in Paris polyphylla SM.
- Detection of Proto-type Compounds of Diosgenin-and Other Spirostanol-Glycosides
- A NOVEL RESIN GLYCOSIDE, MERREMIN (TUGUAJALAPIN X DIMER), FROM MERREMIA HUNGAIENSIS
- Three Glycosphingolipids Having the Phosphocholine Group from the Crude Drug "Jiryu" (The Earthworm, Pheretima asiatica)
- Resin Glycosides. XVIII. Determination by Mosher's Method of the Absolute Configurations of Mono- and Dihydroxyfatty Acids Originated from Resin Glycosides
- Resin Glycosides. VII. : Reinvestigation of the Component Organic and Glycosidic Acids of Pharbitin, the Crude Ether-Insoluble Resin Glycoside ("Convolvulin") of Pharbitidis Semen (Seeds of Pharbitis nil)
- Resin Glycosides. IV. Two New Resin Glycosides, Muricatins VII and VIII : from the Seeds of Ipomoea muricata
- Resin Clycosides. III : Isolation and Structural Study of the Genuine Resion Glycosides, Muricatins I : VI, from the Seeds of I pomoea muricata
- Resin Glycosides. II. : Identification and Characterization of the Component Organic and Glycosidic Acids of the Crude Resin Glycoside from the Seeds of Ipomoea muricata
- The X-Ray Analysis of Caesalpin J from Sappan Lignum
- The Constituents of Paris verticillata M. v. BIEB.
- Studies on the Constituents of Momordica cochinchinensis SPRENG. I. Isolation and Characterization of the Seed Saponins, Momordica Sapponins I and II
- Kikuba-saponin. (1). (Saponins of Japanese Dioscoreaceae. X.)
- Resin Glycosides. XV. Simonins I-V, Ether-Soluble Resin Glycosides (Jalapins) from the Roots of Ipomoea batatas (cv. Simon)
- Digitalis Saponins. III. Enzymatic Hydrolysis of Leaf Saponins of Digitalis purpurea L.
- Digitalis Saponins. II. Leaf Saponins of Digitalis purpurea L.
- Digitalis Saponins. I. Seed Saponins of Digitalis purpurea L. (Commercial "Digitonin")
- Studies on the Agalwood (Jinko). VIII. : Structures of Bi-phenylethylchromone Derivatives
- Studies on the Constituents of Momordica charantia L. I. Isolation and Characterization of Momordicosides A and B, Glycosides of a Pentahydroxy-cucurbitane Triterpene
- Pericarp Saponins of Akebia quinata DECNE. II. Arjunolic and Norarjunolic Acids, and Their Glycosides
- Pericarp Saponins of Akebia quinata DECNE. I. Glycosides of Hederagenin and Oleanolic Acid
- Dehydro-para-asebotin, a New Chalcone Glucoside in the Flowers of Gnaphalium affine D. DON
- A New Diosgenin Glycoside, Aspidistrin, from Aspidistra elatior BLUME
- Seed Saponins of Akebia quinata DECNE. II. Hederagenin 3,28-O-Bisglycosides
- Studies on Resin Glycosides. III. Complete Structures of Pharbitic Acids C and D
- Studies on Resin Glycosides. II. Unhomogeneity of "Pharbitic Acid" and Isolation and Partial Structures of Pharbitic Acids C and D, the Major Constituents of "Pharbitic Acid"
- Studies on Resin Glycosides. I. Reinvestigation of the Components of Pharbitin, a Resin Glycoside of the Seeds of Pharbitis Nil CHOISY
- A New Xanthone C-Glucoside, Position Isomer of Mangiferin, from Anemarrhena asphodeloides BUNGE
- A Mangiferin Monomethyl Ether from Mangifera indica L.
- Partial Methylation with Diazomethane of the Sugar Moiety of Some C- and O-D-Glucopyranosides
- Isolation and Identification of Swertisin from the Leaves of Desmodium caudatum A.P. de CANDOLLE
- Octa (Per)-, Hepta- and Mono-Acetates of Dioscin
- Structures of Prosapogenin-B and -A of Dioscin and Cooccurrence of B with Dioscin in the Rhizoma of Dioscorea Tokoro MAKINO
- A Mangiferin Monomethyl Ether from Mangifera indica L.
- Saponins of Timo (知母 : Anemarrhenae Rhizoma). II. Structure of Timosaponin A-III.
- Reduction of 1-Methyl-3-and-4-methoxycarbonyl Pyridinium Iodide with Sodium Borohydride
- Structures of Dioscin, Gracillin, and Kikuba-saponin. (2). (Saponins of Japanese Dioscoreaceae. XI.)
- Resin Glycosides. XIX. Woodrosins I and II, Ether-Insoluble Resin Glycosides from the Stems of Ipomoea tuberosa
- Resin Glycosides. XVI. Marubajalapins I-VII, New Ether-Soluble Resin Glycosides from Pharbitis purpurea
- Resin Glycosides XIV. Quamoclins I-IV, New Ether-Soluble Resin Glycosides (Jalapin) from the Seeds of Quamoclit pennata
- Resin Glycosides. XI. Operculins III, IV, IX, X, XVI, XVII and XVIII, New Ether-Soluble Resin Glycosides of Rhizoma Jalapae Braziliensis (Root of Ipomoea operculata)
- Resin Glycosides. IX. : Operculins I, II, V, VII and VIII, New Ether-Soluble Resin Glycosides of Rhizoma Jalapae Braziliensis(the Roots of Ipomoea operculata)
- Resin Glycosides. VIII. : Four New Glycosidic Acids, Operculinic Acids D, E, F, and G, of the Ether-Soluble Crude Resin Glycosides ("Jalapin") from Rhizoma Jalapae Braziliensis (Roots of Ipomoea operculata)
- Resin Glycosides. V. : Identification and Characterization of the Component Organic and Glycosidic Acids of the Ether-Soluble Crude Resin Glycosides ("Jalapin") from Rhizoma Jalapae Braziliensis (Roots of Ipomoea Operculata)
- THE STRUCTURE OF AH_, NEW TETRAHYDROXY-2-(2-PHENYLETHYL)CHROMONE FROM AGALWOOD
- OPERCULIN I AND II, NEW ETHER-SOLUBLE RESIN GLYCOSIDES ("JALAPIN") WITH FATTY ACID ESTER GROUPS FROM RHIZOMA JALAPAE BRAZILIENSIS (ROOTS OF& IPOMOEA OPERCULATA)
- Studies on the Agalwood (Jinko). VII. : Structures of Phenylethyl-chromone Derivatives AH_7,AH_8 and AH_9
- Furanoid Norditerpenes from Dioscorea Plants. VII. Structures of Diosbulbinosides D and F
- Conversion of Steroid Saponins to the Corresponding Pregnane Glycosides
- Studies on the Plant Sterols and Triterpenes. II. Separation of Stigmasterol, β-Sitosterol and Campesterol, and about So-called "γ-Sitosterol."
- CHARACTERIZATION OF A MINOR COMPOUND, WHICH ACCOMPANIES THE USUAL 22α (R)-0,25β (S)-SPIROSTANOL GLYCOSIDE, AS A NOVEL TYPE OF 22β (S)-0,25α (S) ANALOG
- CO-OCCURRENCE AND HIGH-PERFORMANCE LIQUID CHROMATOGRAPHIC SEPARATION OF THE GLYCOSIDES OF RHODEASAPOGENIN AND ITS ANALOGS WHICH DIFFER IN THE F-RING STRUCTURE
- Studies on the Constituents of the Crude Drug "Fritillariae Bulbus." III. On the Diterpenoid Constituents of Fresh Bulbs of Fritillaria thunbergii MIQ.
- Massenspektren von Triterpensaponin-permethylat des Oleanantyps
- Furanoid Norditerpenes from Dioscoreaceae Plants. I. Diosbulbins A, B and C from Dioscorea bulbifera L. forma spontanea MAKINO et NEMOTO
- Studies on the Constituents of the Stems of Tinospora tuberculata BEUMEE. II. New Diterpenoids, Borapetoside A and Borapetol A
- NOVEL BI-ISOFLAVONOIDS FROM DALBERGIA ODORIFERA
- Seed Saponins of Akebia quinata DECNE I. Hederagenin 3-O-Glycosides
- OLIGOGLYCOSIDES OF SPIROCYCLIC NORTRITERPENOIDS RELATED TO EUCOSTEROL
- A New Spirostanol, 19-Hydroxyyonogenin, from the Aerial Parts of Dioscorea tokoro MAKINO
- Studies on the Constituents of the Aerial Parts of Dioscorea tenuipes FRANCH. et SAVAT. IV. 2β, 3α, 4β-Trihydroxy-5β-pregn-16-en-20-one and Its 2- and 4-Monoacetates
- Isolation and Structure of a New Tokorogenin Glycoside