Radical Cyclization in Heterocycle Synthesis.12. Sulfanyl Radical Addition-Addition-Cyclization(SRAAC) of Unbranched Diynes and Its Application to the Synthesis of A-Ring Fragment of 1α, 25-Dihydroxyvitamin D_3
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概要
- 論文の詳細を見る
Sulfanyl radical addition-addition-cyclization(SRAAC) of unbranched diynes proceeded smoothly to give cyclized exo-olefins, while the sulfanyl radical addition-cyclization-addition(SRACA) of diynes having a quaternary carbon gave cyclized endo-olefins. This method was successfully applied to the synthesis of A-ring fragment of 1α, 25-dihydroxyvitamin D_3.
- 公益社団法人日本薬学会の論文
- 2001-02-01
著者
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NAITO Takeaki
Kobe Pharmaceutical University
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Naito Takeaki
Kobe Pharmaceutical Univ.
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MIYATA Okiko
Kobe Pharmaceutical University
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NAKAJIMA Emi
Kobe Pharmaceutical University
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Miyata Okiko
Kobe Pharmaceutical Univ.
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