A New Electrochemical System for Stereoselective Allylic Hydroxylation of Cholesteryl Acetate with Dioxygen Induced by Iron Picolinate Complexes
スポンサーリンク
概要
- 論文の詳細を見る
The oxygenation reaction of cholesteryl acetate 1 was examined with the Fe^<III>(PA)_3/O_2/MeCN system using an electrochemical method. The constant potential technique gave mainly the 7-hydroxylated product stereoselectively, along with the 7-oxo product. This oxygenation system is mechanistically unique, requiring iron catalyst, dioxygen, and both cathode and anode.
- 公益社団法人日本薬学会の論文
- 2004-06-01
著者
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Okamoto I
Showa Pharmaceutical University
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Okamoto Iwao
Fujisaki Institute Hayashibara Biochemical Laboratories Inc.
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TAKEYA Tetsuya
Showa College of Pharmaceutical Sciences
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KOTANI Eiichi
Showa Pharmaceutical University
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Takeya T
Showa Pharmaceutical University
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Kotani E
Showa Pharmaceutical University
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Kotani Eiichi
Showa College Of Pharmaceutical Sciences
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Okamoto Iwao
Showa Pharmaceutical University
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FUNAKI Wataru
Showa Pharmaceutical University
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NAKAYA Kyosuke
Showa Pharmaceutical University
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