Selective Allylic Hydroxylation of Octahydronaphthalene Derivatives with a Bridgehead Double Bond Using Electrochemical Method with Iron Picolinate Complexes
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概要
- 論文の詳細を見る
The combination of electrolysis and the Fe^<III> (PA)_3/O_2/CH_3CN system was investigated for allylic hydroxylation of octahydronaphthalene derivatives. Substrates with a bridgehead double bond gave the allylic alcohol with α-preference, while non-bridgehead olefin did not react smoothly. This system is a useful tool for α-selective allylic hydroxylation of octahydronaphthalene derivatives with a bridgehead double bond as model compounds for the AB fused ring of cholesterols.
- 公益社団法人日本薬学会の論文
- 2005-02-01
著者
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Okamoto I
Showa Pharmaceutical University
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Okamoto Iwao
Fujisaki Institute Hayashibara Biochemical Laboratories Inc.
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TAKEYA Tetsuya
Showa College of Pharmaceutical Sciences
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KOTANI Eiichi
Showa Pharmaceutical University
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Takeya T
Showa Pharmaceutical University
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Kotani E
Showa Pharmaceutical University
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Kotani Eiichi
Showa College Of Pharmaceutical Sciences
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Okamoto Iwao
Showa Pharmaceutical University
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FUNAKI Wataru
Showa Pharmaceutical University
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NOBUCHIKA Sachiyo
Showa Pharmaceutical University
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SAWAMURA Mika
Showa Pharmaceutical University
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