Local Structure of Intercalants in Layered Compound Cu_<0.15>Ti_<1.08>S_2
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概要
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X-ray measurements have been performed on the structure of layered compound Cu_<0. 15>Ti_<1.08>S_2 at room temperature. Weak diffuse scatterings at (1/2, 0, 3/2), (1/2, 1/2, 3/2) and (1, 1/2, 3/2) in reciprocal space are observed. This reveals that both the intercalated copper atoms and self-intercalated titanium atoms are three-dimensionally correlated with each other and the stacking sequence αβαβ・・・is deduced. By analyzing diffuse intensity, the short-range order (SRO) parameters were determined. A 2×2 in-plane ordered structure is expected for the low temperature phase. The estimated in-plane and interlayer correlation lengths are about 12 A.
- 社団法人日本物理学会の論文
- 1993-10-15
著者
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Ohshima Ken-ichi
Institute Of Applide Physics University Of Tsukuba
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Maruta Ryo
Institute of Applied Physics, University of Tsukuba
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Makita Atsuya
Institute of Applied Physics, University of Tsukuba
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Makita Atsuya
Institute Of Applied Physics University Of Tsukuba
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Maruta Ryo
Institute Of Applied Physics University Of Tsukuba
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