Statistical Mechanics of One-Dimensional Systems. II : Multicomponent Gas with Intermolecular Potentials of Infinite Range and of Infinitesimal Depth
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概要
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The model of one-dimensional multicomponent gas is proposed in which the particles have hard cores of diameter σ and interparticle (attractive) potentials -2a_<ij>/L, a_<ij>(>0) being a constant (characteristic of the pair of the i-th and j-th species of particles) and L the length of the gas. The partition function and the thermodynamic properties for this model are exactly calculated; a natural extension of van der Waals' equation of state to the multicomponent system is obtained. the entropy of mixing is studied for the present model. Deviations from Raoult's law in the binary solution represented by the present model are discussed. The thermodynamic properties of the dilute solution represented by the present model are examined.
- 理論物理学刊行会の論文
- 1982-06-25
著者
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Takano Takehiko
Department Of Applied Physics Faculty Of Engineering Osaka University
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Takano Takehiko
Department Of Applied Physics Osaka University
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IKEDA Kazuyosi
Department of Applied Physics, Osaka University
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Ikeda Kazuyosi
Department Of Applied Physics Faculty Of Engineering Osaka University
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TAKANO Takehiko
Department of Applied Physics, Faculty of Engineering Osaka University
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