Generalized Theory of Condensing Systems. VI : Examples of Systems Satisfying the G-Condition
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The equation of state for gases and the condensation phenomena are investigated on the basis of the concept of cluster in statistical mechanics. First, a simple (but rather assumptive) system satisfying the G-condition (imposed on the volume-dependent cluster integrals for deducing condensation in a previous paper) is discussed. The system behaves as an ideal gas and condenses at a certain density, the condensation point being a "non-analytical" singularity. Next, sufficient conditions for the validity of the G-condition are given. They are concerned with the ratio of the volume-dependent cluster integral to the limiting cluster integral for infinite volume, and are considered to be satisfied by classical real systems. It is inferred that the condensation of classical real systems occurs at an "analytical" singularity.
- 理論物理学刊行会の論文
- 1976-04-25
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