Effects of Redox of Cu-Species in Copper-Strontium Hydroxyapatites on the Oxidative Dehydrogenation of Propane
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概要
- 論文の詳細を見る
Although it is generally accepted that the catalytic activities of hydroxyapatites for the oxidative dehydrogenation of propane decrease upon addition of CCl4 into the feedstream, greater and stable activities have been found with copper-strontium hydroxyapatites (Cu-SrHAp) in the presence of CCl4. X-ray diffraction and X-ray absorption fine structure analyses of the catalysts used for the oxidation in the presence and absence of CCl4 demonstrate that deep reduction of Cu2+ to Cu0 of Cu-species in Cu-SrHAp during the oxidation is suppressed by the introduction of CCl4, resulting in an enhancement of the activities of the catalysts in the presence of CCl4.
- 社団法人 化学工学会の論文
- 2003-02-01
著者
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MORIGA Toshihiro
Department of Chemical Science and Technology, Graduate School of Advanced Technology and Science, T
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Hayashi H
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
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Sugiyama S
Department Of Chemical Science And Technology Faculty Of Engineering The University Of Tokushima
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HAYASHI Hiromu
Department of Chemical Science and Technology, Faculty of Engineering, University of Tokushima
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Hayashi H
Toyota Central Res. And Develop. Labs. Inc.
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Hayashi Hiromu
Department Of Chemical Science And Technology Faculty Of Engineering The University Of Tokushima
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Sugiyama Shigeru
Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima
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MITSUOKA HIROMICHI
Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima
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SHONO TOMOTAKA
Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima
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Sugiyama Shigeru
Department Of Advanced Materials Institute Of Technology And Science The University Of Tokushima
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Shono Tomotaka
Department Of Chemical Science And Technology Faculty Of Engineering The University Of Tokushima
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Moriga T
Department Of Chemical Science And Technology Faculty Of Engineering The University Of Tokushima
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Moriga Toshihiro
Department Of Chemical Science And Technology Faculty Of Engineering The University Of Tokushima
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Mitsuoka Hiromichi
Department Of Chemical Science And Technology Faculty Of Engineering The University Of Tokushima
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林 久治
Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima
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