OXIDATIVE DEHYDROGENATION OF ETHANE IN THE PRESENCE AND ABSENCE OF TETRACHLOROMETHANE OVER MAGNESIUM SULPHATE
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概要
- 論文の詳細を見る
The oxidative dehydrogenation of ethane in the presence and absence of tetrachloromethane (TCM) has been investigated over MgSO4 at reaction temperatures between 723 and 998 K. Although the conversion of ethane over MgSO4 was increased on addition of TCM to the feedstream, the ethylene selectivity was not influenced except at 723 K. The results of XRD and XPS measurements suggest that MgCl2 is formed on the surface of the the catalyst from the vapor phase TCM and may be responsible for the effects observed in the presence of TCM. At reaction temperatures greater than 898 K, higher conversion of ethane can be attributed to the formation of MgO from the decomposition of MgSO4.
- 社団法人 化学工学会の論文
著者
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Sugiyama S
Department Of Chemical Science And Technology Faculty Of Engineering The University Of Tokushima
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HAYASHI Hiromu
Department of Chemical Science and Technology, Faculty of Engineering, University of Tokushima
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Hayashi H
Toyota Central Res. And Develop. Labs. Inc.
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Hayashi Hiromu
Department Of Chemical Science And Technology Faculty Of Engineering The University Of Tokushima
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Sugiyama Shigeru
Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima
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SATOMI Kohji
Department of Chemical Science and Technology, The University of Tokushima
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TANAKA Michie
Shikoku Research Institute Inc.
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JOHN B.
Department of Chemistry and the Guelph-Waterloo Centre for Graduate Work in Chemistry, university of
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Sugiyama Shigeru
Department Of Advanced Materials Institute Of Technology And Science The University Of Tokushima
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Satomi Kohji
Department Of Chemical Science And Technology The University Of Tokushima
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John B.
Department Of Chemistry And The Guelph-waterloo Centre For Graduate Work In Chemistry University Of
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