Oxidative Coupling and Partial Oxidation of Methane over Solid Catalysts in the Presence and Absence of Tetrachloromethane as a Gas-Phase Additive
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概要
- 論文の詳細を見る
Our recent studies on the oxidation of methane in the presence and absence of tetrachloromethane (TCM) over a variety of solid catalysts have been summarized together with those of the oxidation of related hydrocarbons. The catalytic activities were generally improved by the addition of TCM and the improvement was strongly dependent on the chlorine species formed over the surface of the catalysts during the oxidation with TCM. However no effects of the introduction of TCM into the feedstream were observed on highly active catalysts such as Li/MgO, Sm_2O_3, and La_2O_3. Various X-ray analyses of the catalysts previously employed in the oxidation are also described in order to clarify the nature and source of the introduction of TCM.
- 九州大学の論文
- 1996-11-12
著者
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Sugiyama Shigeru
Department Of Advanced Materials Institute Of Technology And Science The University Of Tokushima
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Sugiyama Shigeru
Department Of Chemical Science And Technology Faculty Of Engineering The University Of Tokushima
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