Improvement of Crystallographic Quality of Electroplated Copper Thin-Film Interconnections for Through-Silicon Vias
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概要
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The relationship between the electrical properties and crystallographic quality (crystallinity) of electroplated copper thin-film interconnections was investigated. The crystallinity of the grains and grain boundaries of the interconnections was evaluated on the basis of the image quality (IQ) value obtained by electron back-scatter diffraction (EBSD) analysis. The electrical properties of the interconnections vary markedly depending on their crystallinity. The crystallinity also changed markedly as functions of electroplating conditions and the annealing temperature after electroplating. Although the electro migration (EM) resistance of the annealed interconnection was improved, stress-induced migration (SM) was activated by a high residual stress after annealing. To improve electrical reliability without heat treatment after electroplating, the effects of the seed layer under the interconnections on the crystallinity were investigated. As a result, the crystallinity was improved by changing the seed layer from Cu to Ru. In addition, the decrease in current density during electroplating also improved the crystallinity. Therefore, both introducing the Ru seed layer and decreasing the current density during electroplating are effective for developing highly reliable copper interconnections.
- 2013-04-25
著者
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Saito Naoki
Department Of Cardiology Kurashiki Central Hospital
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Asai Osamu
Department Of Clinical Oncology And Hematology School Of Medicine The Jikei University
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Miura Hideo
Fracture And Reliability Research Institute Graduate School Of Engineering Tohoku University
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Furuya Ryosuke
Department Of Anesthesiology And Intensive Care Medicine Yokohama City University Graduate School Of
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Suzuki Ken
Fracture And Reliability Research Institute Graduate School Of Engineering Tohoku University
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Furuya Ryosuke
Department of Nanomechanics, Graduate School of Engineering, Tohoku University, Sendai 980-8579, Japan
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Murata Naokazu
Fracture and Reliability Research Institute, Tohoku University, Sendai 980-8579, Japan
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MIURA Hideo
Fracture and Reliability Research Institute (FRRI), Graduate School of Engineering, Tohoku University
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MURATA Naokazu
Fracture and Reliability Research Institute, Graduate School of Engineering, Tohoku University
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SUZUKI Ken
Fracture and Reliability Research Institute (FRRI), Graduate School of Engineering, Tohoku University
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Saito Naoki
Department of Nanomechanics, Graduate School of Engineering, Tohoku University, Sendai 980-8579, Japan
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