Surface Relief Formation in Azobenzene-Containing Polymers Using 325 nm Holography
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概要
- 論文の詳細を見る
Surface relief (SR) formation in polymethacrylate films with azobenzene side groups was investigated via a holographic method using 325 nm He--Cd laser, which generated stable cis isomers. Because the azobenzene molecules underwent both photoinduced reorientation and photoisomerization according to the polarization and intensity distribution of the interference beams, formation of the SR structure depended on both the exposure energy and polarization distribution. For intensity holography, both the photogenerated cis isomer distribution and polarization direction of the exposed beams played important roles in SR formation, which accompanied the molecularly reoriented SR structure. For polarization holography, a small SR structure accompanied the periodical molecular orientation in the initial stage of polarization holography due to uniform distribution of cis isomer. However, a SR structure larger than that generated by intensity holography was produced in the photostationary state.
- 2012-02-25
著者
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Kawatsuki Nobuhiro
Department Of Applied Chemistry Himeji Institute Of Technology
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Ono Hiroshi
Department Of Agronomy Faculty Of Agriculture Tottori University
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Emoto Akira
Electronics And Photonics Research Institute National Institute Of Advanced Industrial Science And Technology (aist)
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Nishioka Emi
Department Of Materials Science And Chemistry Graduate School Of Engineering University Of Hyogo
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Nishioka Emi
Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo, Himeji, Hyogo 671-2280, Japan
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Emoto Akira
Electronics and Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan
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Kawatsuki Nobuhiro
Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo, Himeji, Hyogo 671-2280, Japan
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Kondo Mizuho
Department of Material Science and Chemistry, Graduate School of Engineering Science, University of Hyogo, Himeji, Hyogo 671-2280, Japan
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