Extremely High Degree Photoinduced In-Plane Reorientation in Azobenzene-Containing Polymer Liquid Crystal Film Using 633 nm Light
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概要
- 論文の詳細を見る
The thermally enhanced photoinduced reorientation behavior of liquid crystalline (LC) polymethacrylate films comprising 4-methoxyazobenzene side groups with different spacer lengths between the azobenzene group and the polymer backbone was investigated based on axis-selective $Z$-to-$E$ photoisomerization using linearly polarized (LP) 633 nm light and thermal amplification of the photoinduced anisotropy. A high-order in-plane reorientation parallel to the polarization ($\mathbf{E}$) of LP 633 nm light was accomplished regardless of the spacer length. We found that the initial orientation of the mesogenic groups played an important role in the reorientation, and clarified the reorientation mechanism by polarization absorption spectroscopy.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2005-01-15
著者
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EMOTO Akira
Department of Electrical Engineering, Nagaoka University of Technology
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Kawatsuki Nobuhiro
Department Of Applied Chemistry Himeji Institute Of Technology
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Ono Hiroshi
Department Of Agronomy Faculty Of Agriculture Tottori University
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Kawatsuki Nobuhiro
Department of Materials Science and Chemistry, Himeji Institute of Technology, University of Hyogo, 2167 Shosha, Himeji 671-2201, Japan
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Uchida Emi
Department of Materials Science and Chemistry, Himeji Institute of Technology, University of Hyogo, 2167 Shosha, Himeji 671-2201, Japan
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Uchida Emi
Department of Applied Chemistry, Himeji Institute of Technology, 2167 Shosha, Himeji 671-2201, Japan
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