Rh(I)-Catalyzed Intramolecular Carbonylative [2+2+1] Cycloaddition Reaction: Preparation of Bicyclo[5.3.0]decadienones with Substituted Cyclopentenone Frameworks
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概要
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The [RhCl(CO)2]2-catalyzed [2+2+1] cycloaddition of bis(allene)s, which have a substituent at the allenic terminus, produced the 8-substituted bicyclo[5.3.0]deca-1(10),6-dien-9-one frameworks. The synthesis of 8,10-dimethylbicyclo[5.3.0]deca-1(10),6-dien-9-one could also be achieved from the bis(1,1,3-trisubstituted-allene).
- 公益社団法人 日本薬学会の論文
著者
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Mukai Chisato
Division Of Pharmaceutical Sciences Graduate School Of Natural Science And Technology Kanazawa Unive
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Inagaki Fuyuhiko
Division Of Molecular Physiology The Tokyo Metropolitan Institute Of Medical Science
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Ogawa Kumiko
Division Of Pathology National Institute Of Health Sciences
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Hayashi Yujiro
Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University
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HAYASHI Yujiro
Division of Clinical Pharmacology, Research Institute, Suntory Co., Ltd.
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Takahashi Yasuhito
Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University
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Mukai Chisato
Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University
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