Regioselective Intramolecular [3+2] Annulation of Allene-Nitrones

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概要

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• The regioselective intramolecular 1,3-dipolar cycloaddition of the phenylsulfonylallene-nitrone derivatives has been developed. This reaction showed that the distal double bond of the allene exclusively reacted with the nitrone group to produce the bicyclic isoxazolidine derivatives regardless of the substitution pattern on the allenyl moiety.

• 公益社団法人　日本薬学会の論文

著者

• Mukai Chisato

  Division Of Pharmaceutical Sciences Graduate School Of Natural Science And Technology Kanazawa Unive

• Inagaki Fuyuhiko

  Division Of Molecular Physiology The Tokyo Metropolitan Institute Of Medical Science

• Kobayashi Harumi

  Division of Pharmaceutical Sciences, Graduate School of Natural Science and Technology, Kanazawa University

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• Regioselective Intramolecular [3+2] Annulation of Allene-Nitrones
• Rh(I)-Catalyzed Intramolecular Carbonylative [2+2+1] Cycloaddition Reaction: Preparation of Bicyclo[5.3.0]decadienones with Substituted Cyclopentenone Frameworks

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