The reductive coupling of organic halide using hydrazine and a palladium catalyst. II. Homocoupling of 1-iodoalkanes.
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概要
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The hydrogenolysis and dimerization of iodoalkanes were catalyzed by Pd in the presence of an appropriate reducing agent. Hydrazine was found to be effective for the coupling of 1-iodoeicosane to give tetracontane, C<SUB>40</SUB>H<SUB>82</SUB>, in a 74% yield. The yield of the coupling product decreased with the decrease of the number of the carbon atoms in the 1-iodoalkanes. Both alkylhydrazines and alkenes were shown not to take part in the reaction as a reaction intermediate.
- 公益社団法人 日本化学会の論文
著者
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Nakajima Riichiro
Department Of Chemical Engineering And Materials Science Faculty Of Engineering Doshisha University
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Hara Tadashi
Department Of Chemical Engineering And Materials Sciences Faculty Of Engineering Doshisha University
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Morita Kazuhiro
Department Of Chemistry Faculty Of Engineering Science Osaka University
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