Reference materials for the pyrolysis gas-chromatographic determination of ammonia, nitrogen, nitrogen monoxide, carbon monoxide, and carbon dioxide.
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概要
- 論文の詳細を見る
Four compounds are proposed as the reference materials to calibrate the pyrolysis gas chromatograph in the determination of inorganic gases: [Co(NH<SUB>3</SUB>)<SUB>5</SUB>Cl]Cl<SUB>2</SUB> for NH<SUB>3</SUB>, [Co(NH<SUB>3</SUB>)<SUB>5</SUB>NO<SUB>2</SUB>]Cl<SUB>2</SUB> for N<SUB>2</SUB>, [Co(NH<SUB>3</SUB>)<SUB>5</SUB>NO]Cl<SUB>2</SUB> for NO, and PbC<SUB>2</SUB>O<SUB>4</SUB> for both O and CO<SUB>2</SUB>. On pyrolyses, the gas evolution of these compounds were stoichiometric, and the peak area corresponded fairly well to the weight of the compound. Under the condition employed, 7.3–138 μmol of NH<SUB>3</SUB>, 2.2–67 μmol of N<SUB>2</SUB>, 2.0–61 μmol of NO, 0.84–26 μmol of CO, and 2.5–76 μmol of CO<SUB>2</SUB> were analyzed by using 0.5–15 mg of the compounds.
- 公益社団法人 日本化学会の論文
著者
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Abe Naoki
Department Of Agricultural Chemistry Faculty Of Agriculture Tohoku University
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Miyokawa Kikuo
Department of Chemistry, Faculty of Science, Fukuoka University
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Masuda Isao
Department of Chemistry, Faculty of Science, Fukuoka University
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Abe Naoki
Department of Chemistry, Faculty of Science, Fukuoka University
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