Oxidative S-dealkylation reaction of sulfide catalyzed by Co(II)(bzacen).
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概要
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In the oxygenation reaction of alkyl sulfides with Co(II)(bzacen)–O<SUB>2</SUB> system, oxidative S–C bond cleavage (<I>S</I>-dealkylation) was found to take place exclusively. The reactivity of <I>S</I>-dealkylation reaction was dependent markedly on both acidity of α-methylene and steric hindrance of alkyl sulfide. The peroxo-Co(III) species is presumed to be the intermediate in this <I>S</I>-dealkylation reaction.
- 公益社団法人 日本化学会の論文
著者
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Watanabe Yoshihito
Department Of Chemistry Graduate School Of Science Nagoya University
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Oae Shigeru
Deparment of Applied Chemistry Faculty of Engineering Osaka City University
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Watanabe Yoshihito
Department of Chemistry, The University of Tsukuba
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Numata Tatsuo
Department of Chemistry, The University of Tsukuba
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Numata Tatsuo
Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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