The Formation of Sulfur Compounds in the Radiolysis of a Toluene Solution of Sulfur
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概要
- 論文の詳細を見る
The radiolysis of a toluene solution of sulfur has been investigated. The formations of benzyl mercaptan, hydrogen, and hydrogen sulfide have been observed, and their amounts determined under various considerations. The amounts of mercaptan formed increase linearly with the concentration of sulfur, and the reactions seem to proceed through the initial decomposition of toluene to form the benzyl radical, which then opens the S<SUB>8</SUB> ring molecule to form the mercaptan. The <I>G</I>-value of hydrogen formation is considerably larger than that of hydrogen sulfide. Similar studies were made of the systems of toluene - cyclohexane - sulfur and of toluene - carbon disulflde - surfur in order to clarify the nature of the radiolysis of toluene and sulfur.
- 社団法人 日本化学会の論文
著者
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Ando W.
Department of Chemistry Radiation Center of Osaka Prefecture
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Oae Shigeru
Deparment of Applied Chemistry Faculty of Engineering Osaka City University
関連論文
- The Radiation-induced Addition of Hydrogen Sulfide to Propylene
- The Radiation-induced Reactions of Benzene with Sulfur and Sulfur Compounds
- The Radiation-induced Reaction of Benzyl Mercaptan and p-Tolyl Mercaptan in Various Organic Solvents
- The Formation of Sulfur Compounds in the Radiolysis of a Toluene Solution of Sulfur
- The Reactions of Cyclic Sulfilimines with Cyanide Ion and Phosphine: Evidence for Substitution on Trivalent Sulfur
- Physical properties and various reactions of thionitrites and related substances.
- Catalytic oxidation of mercaptans by iodine-hydrogen iodide system in dimethyl sulfoxide.
- Oxidative S-dealkylation reaction of sulfide catalyzed by Co(II)(bzacen).
- Enzymatic oxidation of alkyl sulfides by cytochrome P-450 and hydroxyl radical.
- Mechanisms of enzymatic S-oxygenation of thioanisole derivatives and O-demethylation of anisole derivatives promoted by both microsomes and a reconstituted system with purified cytochrome P-450.
- A New Rearrangement Reaction of Azoxybenzene with Arenesulfonyl Chloride
- The Reaction of Azoxybenzene with Acetic Anhydride
- Nucleophilic substitution on 4-methylbenzyl thiocyanate with nucleophiles.
- Mechanism of the Oxygen Exchange Reaction of n-Butyl Methyl Sulfoxide in Sulfuric Acid
- The Reaction of 3H-1,2-Benzodithiole-3-thione with Diphenyldiazomethane
- Kinetic Study of the Pyrolysis of 1- and 2-Phenylethyl Phenyl N-Tosylsulfilimines
- Sulfilimine. XVII. Syntheses and Reactions of N-Carbamoylsulfilimines
- The Reaction of Elemental Sulfur with Organic Compounds. IV. The Reactions of N-Arenesulfonylsulfilimine and Sulfoximine with Sulfur and Diaryl Disulfide
- Elimination and nucleophilic substitution on nitrogen atom. Reactions of -O-aroyl-N,N-di(p-substituted benzyl)- and O-aroyl-N-benzoyl-N-benzylhydroxylamines with various nucleophiles in dipolar aprotic solvents.
- A Novel Reduction of the O-(3,5-Dinitrobenzoyl)-N,N-(aroylary)hydroxylamines by the Cyanide Ion in Dipolar Aprotic Solvents
- Intramolecular stereospecific Pummerer reactions of aryl (substituted-methyl) sulfoxides bearing electron-withdrawing groups with acetic anhydride.
- Deoxygenation of tertiary amine oxides with carbon disulfide.
- Predominant intramolecular Pummerer reactions of substituted benzyl p-tolyl sulfoxides with acetic anhydride.
- Enzymatic oxygenation of sulfides with cytochrome P-450 from rabbit liver. Stereochemistry of sulfoxide formation.
- Unusual reaction of azoxybenzenes with p-toluenesulfonic acid in acetic anhydride.
- Oxygen-18 Scrambling Reaction of Aroyl Alkyl Carbonates
- Reinvestigation of the mechanism of the reaction of N,N-dimethylaniline N-oxide with acetic anhydride.
- Reaction of haloazoxybenzenes with sulfuric acid.
- Reaction of Sulfoxides with Acylating Reagents. IV. The Catalytic Effect of Both the Brönsted and Lewis Acids in the Oxygen Exchange Reaction of Diaryl Sulfoxides with Acetic Anhydride
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- Reaction of Sulfoxides with Acylating Reagents. III. Mechanism of the Reactions of Phenyl Methyl Sulf oxide with Acetic Anhydride
- A cross-coupling reaction of methylsulfinylarene.
- Intermolecular Pummerer rearrangement reactions of alkyl phenyl and dialkyl sulfoxides with acetic anhydride.
- Tracer Study of the Reactions of Diphenyl Sulfone and Diphenyl Sulfoxide with Diphenyl Disulfide
- The Photochemical Degradation of Diphenyl Sulfone-1-14C
- Synthesis and reaction of 2,2'-biquinolyl.
- Thermal curtius rearrangement of N-acyl-S,S-diphenylsulfilimine.
- Catalytic reduction of sulfoxide by bromine-hydrogen bromide system.
- Nucleophilic Substitution on Trivalent Nitrogen Atom. Menschutkin Type Reaction of O-2,4-Dinitrophenylhydroxylamine with Uncharged Nucleophiles
- Pyrolysis of S-(2-(phenylthio-, phenylsulfinyl-, and phenylsufonyl)-ethyl)-N-p-tosylsulfilimine.