Tracer Study of the Reactions of Diphenyl Sulfone and Diphenyl Sulfoxide with Diphenyl Disulfide
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概要
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Diphenyl sulfoxide and diphenyl sulfone were found to react with diphenyl disulfide at elevated temperatures, forming in both reactions diphenyl sulfide and sulfur dioxide. On the basis of <SUP>35</SUP>S and <SUP>14</SUP>C tracer experiments, these reactions were found to proceed through quite different mechanistic routes, <I>viz.</I>, S–O bond fission in the case of sulfoxide and C–S bond fission in sulfone. The reactions apparently proceed through the attack of the thiyl radical on the sulfoxide and sulfone functions. Further mechanistic details of the reactions are discussed.
- 公益社団法人 日本化学会の論文
著者
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Oae Shigeru
Deparment of Applied Chemistry Faculty of Engineering Osaka City University
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Nakai Mamoru
Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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Tsuchida Yoshiyuki
Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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