The crystal and molecular structure of bis(methanol)-.ALPHA.,.BETA.,.GAMMA.,.DELTA.-tetraphenylporphinatomanganese(III) perchlorate-methanol. A molecular structure relevant to the intermediate-spin six coordinate iron(III) porphyrin.
スポンサーリンク
概要
- 論文の詳細を見る
Bis(methanol)-α,β,γ,δ-tetraphenylporphinatomanganese(III) perchlorate crystallizes as the methanol solvate in the triclinic system, space group P\bar1, <I>a</I>=16.225(8), <I>b</I>=13.167(7), <I>c</I>=10.793(5) Å, α=106.51(5)°, β=100.36(5)°, γ=101.60(5)°, and <I>Z</I>=2. The structure was determined by the heavy-atom method and the block-diagonal least-squares refinement using a total of 9992 reflections. The final <I>R</I> and <I>R</I><SUB>w</SUB> values are 6.3 and 7.1%, respectively. Two slightly different but substantially identical coordination spheres of high-spin Mn(III) porphyrin were revealed. The long axial Mn–O(methanol) bond distance and medium-sized porphyrin core were emphasized as structural characteristics in relation to the intermediate-spin iron(III) porphyrin.
- 公益社団法人 日本化学会の論文
著者
-
Iitaka Yoichi
Faculty Of Medicine Teikyo University
-
Anzai Kazunori
Department Of Bioregulation Research National Institute Of Radiological Sciences
-
Hatano Keiichiro
Department Of Pharmaceutical Science Nagoya City University
関連論文
- Studies on Tetrahydroisoquinolines. XXIX. : Reaction of 7-Acetoxy-1,2,3,4,6,7-hexahydro-1-(2-(3',4'-dimethoxy- or 3',4'-methylenedioxyphenyl)ethyl)-7-methoxy-2-methyl-6-oxo-isoquinoline (о-Quinol Acetate) with Acetic Anhydride in the Presence of Acid(Orga
- Vascular Homeostasis Regulators, Edn1 and Agpt2, are Upregulated as a Protective Effect of Heat-treated Zinc Yeast in Irradiated Murine Bone Marrow
- Novel Approach to In Vivo Screening for Radioprotective Activity in Whole Mice : In Vivo Electron Spin Resonance Study Probing the Redox Reaction of Nitroxyl
- Further Studies on the Structure of Retigeranic Acid
- Crystal Structures and Acetonitrile Exchange of Palladium(II) Complexes with Bis(3-aminopropyl)amine and Diethylenetriamine. Effects of Ion-Pair Formation
- MICROBIOLOGICAL ASYMMETRIC INDUCTION OF 4,9-DIMETHYL-3,5-DIOXO-Δ^-OCTALIN
- Heat-Treated Mineral-Yeast as a Potent Post-irradiation Radioprotector
- A Novel Antileukemic Tropoloisoquinoline Alkaloid, Pareirubrine, from Cissampelos pareira
- Synthesis of Transmembrane Segment Peptides and Its Analogs of A Single Spanning Protein, Isk, Forming Potassium Channel and Its Channel Formation Activity
- Studies on Association Behavior of Transmembrane Segment of Influenza Virus M2 Protein in Lipid Bilayers
- Conformational Analysis of Curdione and Neocurdione(Organic,Chemical)
- E-1-5 The Structure of Enmein : the X-ray Study of Acetyl-bromoacetyldihydroenmein(Mainly physico-chemical methods)
- Measurement of Free Radicals in Living Mice by In Vivo ESR Spectroscopy
- PA32 ABSOLUTE STRUCTURE OF OPTICALLY ACTIVE DIELS-ALDER TYPE ADDUCTS FROM THE MORUS ROOT BARK
- NITROSYL COMPLEXES OF IRON PORPHYRINS
- ON THE SPIN STATE OF SIX-COORDINATE IRON (III) PORPHYRINS IN WHICH THE AXIAL LIGANDS ARE ISOTHIOCYANATE AND PYRIDINE
- CRYSTAL AND MOLECULAR STRUCTURE OF ZINC TETRAARYL-PORPHYRIN ATROPISOMERS
- Cytotoxic Triterpene from Aster tataricus
- The Stereostructure of (1R, 10R)-epoxy-(-)-1, 10-dihydrocurdione from Curcuma wenyujin
- Formation of Anthraquinones, Hydroanthracene and Flavonoid by the Callus Culture of Cassia torosa
- Crystallization of Calmodulin Complexed with Bee Venom Melittin
- X-Ray Diffraction Studies of the Molecular Complexes of Tetracycline Salts
- X-ray and neutron-diffraction study of a stereoselectively deuterated benzyl t-butyl sulfoxide. A revised configuration assignment for the chiral carbon atom due to isotopic substitution.
- Molecular structure of 3,4,6-tri-O-acetyl-1,2-O-((1S)-1-(2-p-bromophenyl)-9H-imidazo(1,2-a)benzimidazol-3-yl)ethylidene)-.ALPHA.-D-glucopyranose acetone solvate.
- Synthesis of dichlorocyclobuta[b]benzofuran-2a-carboxylic derivatives and 3-(trichloroethenyl)coumarin through cross photocycloadduct of coumarin and tetrachloroethylene.
- X-ray crystal structure of 7,16,24,33-tetrathia[3]paracyclo[3](1,3)-ferroceno[3]paracyclo[3](1,3)ferrocenophane.
- Isolation and structure determination of a mutagenic substance in L-lysine pyrolysate.
- Isolation and structure determination of mutagenic substances in L-glutamic acid pyrolysate.
- Transformation of D:A-friedo-18.BETA.-lup-19-en-3-one into D:B-friedo-18.BETA.,19.ALPHA.H-lup-5-en-3.BETA.-ol and a comment on the structure of guimarenol.
- Acid-catalyzed backbone rearrangement of 5,6-epoxyalnusanes and preparation of daturadiol.
- A highly selective transannular route to trans-trans-1,2,3,3a,4,5,9,10,10a,10b-decahydropyrenes from (2.2)metacyclophanes.
- Synthesis and kinetic investigation of the atropisomerization of meso-tetra(2-cyanophenyl)porphine.
- Structure determination of bitter principles of Ailanthus altissima. Structures of shinjulactones B,D, and E.
- Boron trifluoride etherate-catalyzed backbone rearrangement of 13.BETA.,18.BETA.-epoxybaccharan-3.BETA.-yl acetate. A sequential migration of two methyl groups and a hydride in biogenetic direction.
- Crystallization of human recombinant interleukin-2.
- Redox reaction of the central metal ions coordinated to tetra-(p-sulfophenyl)porphine(TPPS). I. Photoreduction of Co(III)TPPS by methanol and 2-propanol.
- The crystal and molecular structure of bis(methanol)-.ALPHA.,.BETA.,.GAMMA.,.DELTA.-tetraphenylporphinatomanganese(III) perchlorate-methanol. A molecular structure relevant to the intermediate-spin six coordinate iron(III) porphyrin.
- Boron trifluoride etherate-catalyzed backbone rearrangement of 5.ALPHA.,10.ALPHA.-epoxyalnusan-3.BETA.-yl acetate and partial synthesis of isomultiflorenol.
- Synthesis and X-ray crystal structure of [54](1,2,3,4)ferrocenophane.
- Atropisomerism of zinc tetrakis(o-cyanophenyl)porphyrins. The crystal structure of the .ALPHA..BETA..ALPHA..BETA.-isomer and the atropisomerization rates.
- Crystal and Molecular Structure of (−)-erythro-1′-(2,5-Dimethoxyphenyl)-3′-diethylaminobutyl Acetate Hydrobromide
- The Crystal Structure of Ascochlorin p-Bromobenzenesulfonate
- The Crystal and Molecular Structures of a 3 : 2 Adduct of Acetylene and Isonitrile Derivatives
- Studies on lactams. VII. Conformation of D-glucono-1,5-lactam.
- Determination of Stereostructure of Neocurdione Isolated from Curcuma wenyujin