Catalytic hydrogenolysis of 1,1-difluoro-2-phenyl- and 1,1-difluoro-3-methyl-2-phenylcyclopropane.
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概要
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The title compounds were hydrogenolyzd over PdO or Raney nickel. The C<SUB>2</SUB>–C<SUB>3</SUB> bond of the cyclopropane ring underwent cleavage exclusively over the both catalysts. The contribution of the fluorine substituent to the lengthening and weakening the C<SUB>2</SUB>–C<SUB>3</SUB> bond of the cyclopropane ring seems to become a dominant factor in the regioselectivity.
- 公益社団法人 日本化学会の論文
著者
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Isogai Koji
Department Of Aerospace Engineering Nihonbunri University
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Saito Tetsuji
Department of Applied Chemistry, Faculty of Engineering, Niigata University
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Sakai Jun-ichi
Department of Applied Chemistry, Faculty of Engineering, Niigata University
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Nishizawa Naomi
Department of Applied Chemistry, Faculty of Engineering, Niigata University
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