Catalytic hydrogenolysis of 1,1-dichloro-3-methyl-2-phenylcyclopropane.
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概要
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The title compound was hydrogenolyzed over PdO or Raney nickel. The C<SUB>2</SUB>–C<SUB>3</SUB> bond of the cyclopropane ring underwent cleavage exclusively over PdO. Cleavage of the C<SUB>1</SUB>–C<SUB>2</SUB> and C<SUB>2</SUB>–C<SUB>3</SUB> bonds occurred competitively over Raney nickel. A probable pathway is suggested.
- 公益社団法人 日本化学会の論文
著者
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Isogai Koji
Department Of Aerospace Engineering Nihonbunri University
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Hirabayashi Shigeru
Department of Applied Chemistry, Faculty of Engineering, Niigata University
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