Intramolecular cycloaddition of two acyl-1,4-benzoquinone moieties on photolysis.

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概要

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• Upon irradiation a regio- and stereoselective cycloaddition occurred intramolecularly between two acyl-1,4-benzoquinone moieties connected by a polymethylene bridge. The regio- and stereoselectivities are different from those of the corresponding intermolecular cycloaddition; this was interpreted in terms of the Diels-Alder reaction between an acyl-1,4-benzoquinone moiety and a photochemically produced dienol.

• 公益社団法人 日本化学会の論文

著者

• SATO Mamoru

  Institute for Protein Research, Osaka University

• Maruyama Kazuhiro

  Department Of Chemistry Faculty Of Science Kyoto University

• Tanaka Nobuo

  Institute For Solid State Physics University Of Tokyo

• Miyagi Yo

  Faculty Of Education Kanazawa University

• Tomizu Toshinori

  Faculty of Education, Kanazawa University

• Isogawa Yasuhiro

  Faculty of Education, Kanazawa University

• Kashiwano Hisae

  Faculty of Education, Kanazawa University

• Sato Mamoru

  Institute for Protein Research

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