Studies on the Baudisch Reaction. IV. The Reaction Mechanism
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概要
- 論文の詳細を見る
Mechanism of the Baudisch reaction was investigated using semicarbazide hydrochloride in lieu of hydroxylamine hydrochloride which is one of the reacting components. It was suggested that pyrocatechol-copper-hydroxylamine complex formed as a reaction intermediate is oxidized to <I>o</I>-benzoquinone-copper complex by hydrogen peroxide and one of the carbonyl groups of <I>o</I>-benzoquinone reacts with hydroxylamine hydrochloride to give <I>o</I>-benzoquinone monooxime, <I>i.e.</I> 2-nitrosophenol.
- 公益社団法人 日本化学会の論文
著者
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Maruyama Kazuhiro
Department Of Chemistry Faculty Of Science Kyoto University
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Tanimoto Iwao
Faculty of Home Economics, Kyoto Women's University
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