Syntheses of new optically active organosilanes and their applications for the optical-purity-determining agents.

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概要

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• New optically active organosilicon compounds such as (benzylmethylphenylsilyl)acetic acid (<B>1</B>) and (ethylmethylphenylsilyl)acetic acid (<B>2</B>) were synthesized. Application of these acids as the optical purity determining agents for chiral amines and alcohols were successfully carried out. In addition, it was also revealed that optically active (benzylmethylphenylsilyl)methylamine (<B>3</B>) and [benzylmethyl(<I>o</I>-tolyl)silyl]methylamine (<B>4</B>) are able to be used as the optical purity determining agents for chiral carboxylic acids.

• 公益社団法人 日本化学会の論文

著者

• Ueno Satoshi

  Department Of Cardiovascular Medicine Wakayama Medical University

• Terunuma Daiyo

  Department Of Functional Materials Science Saitama University

• Kato Masato

  Department Of Anesthesiology And Emergency Medicine Tohoku University Postgraduate Medical School

• Nohira Hiroyuki

  Department Of Applied Chemistry Faculty Of Engineering Saitama University

• Kamei Masanao

  Department of Applied Chemistry, Faculty of Engineering, Saitama University

• Uchida Hidekatsu

  Department of Applied Chemistry, Faculty of Engineering, Saitama University

• Terunuma Daiyo

  Department of Applied Chemistry, Faculty of Engineering, Saitama University

• Kato Masato

  Department of Applied Chemistry, Faculty of Engineering, Saitama University

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