The Polymerization of Silacyclopentene and -pentane Derivatives

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概要

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• The polymerization of 1,1,3-trimethyl-1-silacyclopentene-3 (I), 1-methyl-, 1-allyl-1,1-diallyl-1-silacyclopentenes and -pentanes with aluminum chloride was carried out. By means of an IR spectroscopic analysis of the resulting polymers, it was established that not only ring opening but also vinyl polymerization due to the C–C double bond occur in this polymerization. Attempts to polymerize I with other catalysts, such as BF<SUB>3</SUB>·OEt<SUB>2</SUB>, AIBN, KOH, and a Ziegler catalyst, were unsuccessful.

• 公益社団法人 日本化学会の論文

著者

• Terunuma Daiyo

  Department Of Functional Materials Science Saitama University

• Nakamura Shigeyoshi

  Department of Applied Chemistry, Faculty of Science and Engineering, Saitama University

• Araki Tsunao

  Department of Applied Chemistry, Faculty of Science and Engineering, Saitama University

• Sato Tamio

  Department of Applied Chemistry, Faculty of Science and Engineering, Saitama University

• Nagai Norio

  Department of Applied Chemistry, Faculty of Science and Engineering, Saitama University

• Furuichi Mitsuharu

  Department of Applied Chemistry, Faculty of Science and Engineering, Saitama University

• Terunuma Daiyo

  Department of Applied Chemistry, Faculty of Engineering, Saitama University

• Terunuma Daiyo

  Department of Applied Chemistry, Faculty of Science and Engineering, Saitama University

• Araki Tsunao

  Department of Applied Chemistry, Faculty of Engineering, Saitama University

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