The configurations of benzylmethyl(o- or p-tolyl)silylmethylamine and the stereochemistry of the reactions of benzylmethylmethoxyphenylsilane with some organometallic agents.
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概要
- 論文の詳細を見る
Optically active α-amino organosilanes such as benzylmethyl(<I>o</I>- or <I>p</I>-tolyl)silylmethylamine were converted into benzylmethylphenyl(<I>o</I>- or <I>p</I>-tolyl)silane, of which the configurations had been known. From these observations, it was found that (+)- and (−)-benzylmethyl(<I>o</I>- or <I>p</I>-tolyl)silylmethylamine has <I>S</I> and <I>R</I> configuration respectively. Furthermore, the stereochemistry of the reaction of benzylmethyl(methoxy)phenylsilane with some organometallic agents was investigated.
- 公益社団法人 日本化学会の論文
著者
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Nohira Hiroyuki
Department Of Applied Chemistry Faculty Of Engineering Saitama University
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Terunuma Daiyo
Department of Applied Chemistry, Faculty of Engineering, Saitama University
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Senda Kazuhisa
Department of Applied Chemistry, Faculty of Engineering, Saitama University
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Sanazawa Masato
Department of Applied Chemistry, Faculty of Engineering, Saitama University
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